Benzoic acid (1S,2R)-2-((E)-6-tert-butoxycarbonyl-5-oxo-hex-3-enyl)-2-methyl-3-oxo-cyclopentyl ester

Base Information

Chemical Name:Benzoic acid (1S,2R)-2-((E)-6-tert-butoxycarbonyl-5-oxo-hex-3-enyl)-2-methyl-3-oxo-cyclopentyl ester
CAS No.:130313-02-9
Molecular Formula:C₂₄H₃₀O₆
Molecular Weight:414.499
Hs Code.:

Synonyms:Benzoic acid (1S,2R)-2-((E)-6-tert-butoxycarbonyl-5-oxo-hex-3-enyl)-2-methyl-3-oxo-cyclopentyl ester

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Chemical Property of Benzoic acid (1S,2R)-2-((E)-6-tert-butoxycarbonyl-5-oxo-hex-3-enyl)-2-methyl-3-oxo-cyclopentyl ester

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Technology Process of Benzoic acid (1S,2R)-2-((E)-6-tert-butoxycarbonyl-5-oxo-hex-3-enyl)-2-methyl-3-oxo-cyclopentyl ester

There total 7 articles about Benzoic acid (1S,2R)-2-((E)-6-tert-butoxycarbonyl-5-oxo-hex-3-enyl)-2-methyl-3-oxo-cyclopentyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 130313-01-8,130404-66-9
Benzoic acid (1S,2R)-2-((E)-6-tert-butoxycarbonyl-5-hydroxy-hex-3-enyl)-2-methyl-3-oxo-cyclopentyl ester

: 130313-02-9
Benzoic acid (1S,2R)-2-((E)-6-tert-butoxycarbonyl-5-oxo-hex-3-enyl)-2-methyl-3-oxo-cyclopentyl ester

Guidance literature:: With manganese(IV) oxide; In ethyl acetate; for 8h; Ambient temperature;
DOI:10.1139/v92-243

Reference yield:

: 41878-37-9
1β-benzoyloxy-7aβ-methyl-5,6,7,7a-tetrahydroindan-5-one

: 130313-02-9
Benzoic acid (1S,2R)-2-((E)-6-tert-butoxycarbonyl-5-oxo-hex-3-enyl)-2-methyl-3-oxo-cyclopentyl ester

Guidance literature:: Multi-step reaction with 5 steps

2: 1.) BH₃*THF, 2.) pyridinium chlorochromate (PCC) / 1.) THF, 0 deg C, 2 h, 2.) CH₂Cl₂, room temperature, 3 h

3: 73 percent / benzene / 48 h / Heating

4: 1.) Zn, I₂ / 1.) THF, reflux, 1 h, 2.) THF, 0 deg C, 90 min

5: 58 percent / MnO₂ / ethyl acetate / 8 h / Ambient temperature

With manganese(IV) oxide; borane-THF; iodine; pyridinium chlorochromate; zinc; In ethyl acetate; benzene;
DOI:10.1139/v92-243

Reference yield:

: 5292-43-3
bromoacetic acid tert-butyl ester

: 130313-02-9
Benzoic acid (1S,2R)-2-((E)-6-tert-butoxycarbonyl-5-oxo-hex-3-enyl)-2-methyl-3-oxo-cyclopentyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Zn, I₂ / 1.) THF, reflux, 1 h, 2.) THF, 0 deg C, 90 min

2: 58 percent / MnO₂ / ethyl acetate / 8 h / Ambient temperature

With manganese(IV) oxide; iodine; zinc; In ethyl acetate;
DOI:10.1139/v92-243