tert-butyl-[2-(2,2-dimethyl-[1,3]dioxan-5-yl)-5-methyl-cyclohexa-1,4-dienyloxy]-dimethyl-silane

Base Information

• Chemical Name: tert-butyl-[2-(2,2-dimethyl-[1,3]dioxan-5-yl)-5-methyl-cyclohexa-1,4-dienyloxy]-dimethyl-silane
• CAS No.: 896745-84-9
• Molecular Formula: C₁₉H₃₄O₃Si
• Molecular Weight: 338.563
• Mol file: 896745-84-9.mol

Synonyms:tert-butyl-[2-(2,2-dimethyl-[1,3]dioxan-5-yl)-5-methyl-cyclohexa-1,4-dienyloxy]-dimethyl-silane

Chemical Property of tert-butyl-[2-(2,2-dimethyl-[1,3]dioxan-5-yl)-5-methyl-cyclohexa-1,4-dienyloxy]-dimethyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-butyl-[2-(2,2-dimethyl-[1,3]dioxan-5-yl)-5-methyl-cyclohexa-1,4-dienyloxy]-dimethyl-silane

There total 1 articles about tert-butyl-[2-(2,2-dimethyl-[1,3]dioxan-5-yl)-5-methyl-cyclohexa-1,4-dienyloxy]-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tert-butyl-[2-(2,2-dimethyl-[1,3]dioxan-5-yl)-5-methyl-phenoxy]-dimethyl-silane (896745-90-7) → tert-butyl-[2-(2,2-dimethyl-[1,3]dioxan-5-yl)-5-methyl-cyclohexa-1,4-dienyloxy]-dimethyl-silane (896745-84-9)

Guidance literature:

With ammonia; lithium; In tetrahydrofuran; ethanol; cooling;

DOI:10.1021/ol060382z

Reference yield: 86.7%

tert-butyl-[2-(2,2-dimethyl-[1,3]dioxan-5-yl)-5-methyl-cyclohexa-1,4-dienyloxy]-dimethyl-silane (896745-84-9) → 6-(2,2-dimethyl-[1,3]dioxan-5-yl)-3-methyl-cyclohex-3-enone (896745-77-0)

Guidance literature:

With tetrabutyl ammonium fluoride; boric acid; In tetrahydrofuran; water; at 10 ℃;

DOI:10.1021/ol060382z

Reference yield:

tert-butyl-[2-(2,2-dimethyl-[1,3]dioxan-5-yl)-5-methyl-cyclohexa-1,4-dienyloxy]-dimethyl-silane (896745-84-9) → 2-(2,2-dimethyl-[1,3]dioxan-5-yl)-4,5-dihydroxy-5-methyl-cyclohexanone

Guidance literature:

Multi-step reaction with 2 steps

1: 86.7 percent / tetrabutylammonium fluoride; boric acid / tetrahydrofuran; H₂O / 10 °C

2: 92 percent / N-methylmorpholine-N-oxide; osmium tetroxide / tetrahydrofuran; 2-methyl-propan-2-ol; H₂O / 25 °C

With osmium(VIII) oxide; tetrabutyl ammonium fluoride; boric acid; 4-methylmorpholine N-oxide; In tetrahydrofuran; water; tert-butyl alcohol;

DOI:10.1021/ol060382z

upstream raw materials:

tert-butyl-[2-(2,2-dimethyl-[1,3]dioxan-5-yl)-5-methyl-phenoxy]-dimethyl-silane

Downstream raw materials:

6-(2,2-dimethyl-[1,3]dioxan-5-yl)-3-methyl-cyclohex-3-enone