(1R,2R)-1-<(E)-hex-1-enyl>-2-hydroxymethylcyclopropane

Base Information

Chemical Name:(1R,2R)-1-<(E)-hex-1-enyl>-2-hydroxymethylcyclopropane
CAS No.:98392-29-1
Molecular Formula:C₁₀H₁₈O
Molecular Weight:154.252
Hs Code.:

Synonyms:(1R,2R)-1-<(E)-hex-1-enyl>-2-hydroxymethylcyclopropane

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Chemical Property of (1R,2R)-1-<(E)-hex-1-enyl>-2-hydroxymethylcyclopropane

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Technology Process of (1R,2R)-1-<(E)-hex-1-enyl>-2-hydroxymethylcyclopropane

There total 1 articles about (1R,2R)-1-<(E)-hex-1-enyl>-2-hydroxymethylcyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 826-34-6
dimethyl cis-cyclopropane-1,2-dicarboxylate

: 98392-29-1
(1R,2R)-1-<(E)-hex-1-enyl>-2-hydroxymethylcyclopropane

Guidance literature:: Multi-step reaction with 6 steps

1: LAH / diethyl ether / 0.5 h / 0 °C

2: DMAP, TEA / CH₂Cl₂ / 1 h / Ambient temperature

3: 1M NaOH / ethane-1,2-diol; H₂O / 3 °C / lipase (PPL)

4: PCC, NaOAc, molecular sieves / CH₂Cl₂ / 1 h / Ambient temperature

5: 1) NaHMDS / 1) -178 deg C (5 min) to r.t., 2) 110 dec C, 30 min

6: 90 percent / K₂CO₃, MeOH / 0.42 h / Ambient temperature

With methanol; dmap; sodium hydroxide; lithium aluminium tetrahydride; molecular sieve; TEA; sodium acetate; sodium hexamethyldisilazane; potassium carbonate; pyridinium chlorochromate; In diethyl ether; dichloromethane; water; ethylene glycol;
DOI:10.1016/S0040-4020(01)86378-X

Reference yield: 85.0%

: 98392-29-1
(1R,2R)-1-<(E)-hex-1-enyl>-2-hydroxymethylcyclopropane

: 98392-31-5
cis-(1R,2R)-1-formyl-2-<(E)-hex-1-enyl>cyclopropane

Guidance literature:: With molecular sieve; sodium acetate; pyridinium chlorochromate; In dichloromethane; for 0.5h; Ambient temperature;
DOI:10.1016/S0040-4020(01)86378-X