RhH(PPh₃)2(1,2-bis(dimethylsilylbenzene(-2H))

Base Information

• Chemical Name: RhH(PPh₃)2(1,2-bis(dimethylsilylbenzene(-2H))
• CAS No.: 1039067-04-3
• Molecular Formula: C₄₆H₄₇P₂RhSi₂
• Molecular Weight: 820.903
• Mol file: 1039067-04-3.mol

Synonyms:RhH(PPh₃)2(1,2-bis(dimethylsilylbenzene(-2H))

Chemical Property of RhH(PPh₃)2(1,2-bis(dimethylsilylbenzene(-2H))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of RhH(PPh₃)2(1,2-bis(dimethylsilylbenzene(-2H))

There total 4 articles about RhH(PPh₃)2(1,2-bis(dimethylsilylbenzene(-2H)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

Wilkinson's catalyst (14694-95-2) + 1,2-bis(dimethylsilyl)benzene (17985-72-7) → RhH(PPh3)2(1,2-bis(dimethylsilylbenzene(-2H)) (1039067-04-3) + Rh(PPh3)(1,2-bis(dimethylsilyl)benzene)(η1-1,2-bis(dimethylsilylbenzene(-H))*0.5hexane

Guidance literature:

In toluene; (Ar); stirring soln. of rhodium compd. and 2.5 equiv. of silane deriv. in benzene at 50°C for 6 h; evapn., washing with hexane, dissolving in toluene, layering with hexane, isolation of crystals, elem. anal.;

DOI:10.1021/om800151w

Reference yield: 58.0%

hydridotetakis(triphenylphosphine)rhodium(I) (18284-36-1,27497-56-9) + 1,2-bis(dimethylsilyl)benzene (17985-72-7) → RhH(PPh3)2(1,2-bis(dimethylsilylbenzene(-2H)) (1039067-04-3) + Rh(PPh3)(1,2-bis(dimethylsilyl)benzene)(η1-1,2-bis(dimethylsilylbenzene(-H))*0.5hexane

Guidance literature:

In toluene; (Ar); stirring soln. of rhodium compd. and 2.5 equiv. of silane deriv. in benzene at 50°C for 6 h; evapn., washing with hexane, dissolving in toluene, layering with hexane, isolation of crystals, elem. anal.;

DOI:10.1021/om800151w

Reference yield:

RhH3(PPh3)2(1,2-bis(dimethylsilylbenzene(-2H)) (1039067-01-0) → RhH(PPh3)2(1,2-bis(dimethylsilylbenzene(-2H)) (1039067-04-3)

Guidance literature:

In not given; byproducts: H2; (Ar); evacuation of soln. of rhodium compd.; NMR;

DOI:10.1021/om800151w

upstream raw materials:

Wilkinson's catalyst

1,2-bis(dimethylsilyl)benzene

hydridotetakis(triphenylphosphine)rhodium(I)

RhH₃(PPh₃)2(1,2-bis(dimethylsilylbenzene(-2H))

Downstream raw materials:

RhH₃(PPh₃)2(1,2-bis(dimethylsilylbenzene(-2H))

hydridotetakis(triphenylphosphine)rhodium(I)

Refernces