N-tosyl-2-[4-(ethylthio)-5-(2-(2-(2-methoxyethoxy)ethoxy)ethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole

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Chemical Name:N-tosyl-2-[4-(ethylthio)-5-(2-(2-(2-methoxyethoxy)ethoxy)ethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole
CAS No.:1357295-12-5
Molecular Formula:C₂₄H₂₉NO₅S₇
Molecular Weight:635.96
Hs Code.:

Synonyms:N-tosyl-2-[4-(ethylthio)-5-(2-(2-(2-methoxyethoxy)ethoxy)ethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole

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Chemical Property of N-tosyl-2-[4-(ethylthio)-5-(2-(2-(2-methoxyethoxy)ethoxy)ethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole

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Technology Process of N-tosyl-2-[4-(ethylthio)-5-(2-(2-(2-methoxyethoxy)ethoxy)ethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole

There total 8 articles about N-tosyl-2-[4-(ethylthio)-5-(2-(2-(2-methoxyethoxy)ethoxy)ethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 846571-61-7
N-tosyl-2-[4-(ethylthio)-5-(2-cyanoethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole

: 62999-96-6
3,6,9-trioxadecyl iodide

: 1357295-12-5
N-tosyl-2-[4-(ethylthio)-5-(2-(2-(2-methoxyethoxy)ethoxy)ethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole

Guidance literature:: N-tosyl-2-[4-(ethylthio)-5-(2-cyanoethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole; 3,6,9-trioxadecyl iodide; In tetrahydrofuran; for 0.25h; Inert atmosphere;

With cesiumhydroxide monohydrate; In tetrahydrofuran; methanol; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.1021/ja210861v

Reference yield:

: C₁₇H₁₅NO₂S₇

: 62999-96-6
3,6,9-trioxadecyl iodide

: 1357295-12-5
N-tosyl-2-[4-(ethylthio)-5-(2-(2-(2-methoxyethoxy)ethoxy)ethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole

Guidance literature:: In tetrahydrofuran; methanol; at 20 ℃; for 16h; Inert atmosphere;
DOI:10.3762/bjoc.11.125

Reference yield:

: 250687-26-4
4,6-dihydro-N-tosyl-(1,3)-dithiolo[4,5-c]pyrrole-2-one

: 1357295-12-5
N-tosyl-2-[4-(ethylthio)-5-(2-(2-(2-methoxyethoxy)ethoxy)ethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole

Guidance literature:: Multi-step reaction with 4 steps

1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / chlorobenzene / 4 h / Reflux; Inert atmosphere

2: triethyl phosphite / 1.73 h / 130 °C / Inert atmosphere

3: cesiumhydroxide monohydrate / tetrahydrofuran; methanol / 2 h / Inert atmosphere

4: tetrahydrofuran; methanol / 16 h / 20 °C / Inert atmosphere

With cesiumhydroxide monohydrate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; triethyl phosphite; In tetrahydrofuran; methanol; chlorobenzene;
DOI:10.3762/bjoc.11.125