fac-W(CO)3(PMe3)(η(2)-1,1'-bis(diphenylphosphino)ferrocene)

Base Information

• Chemical Name: fac-W(CO)3(PMe3)(η(2)-1,1'-bis(diphenylphosphino)ferrocene)
• CAS No.: 163162-57-0
• Molecular Formula: C₄₀H₃₇FeO₃P₃W
• Molecular Weight: 898.35
• Mol file: 163162-57-0.mol

Synonyms:fac-W(CO)3(PMe3)(η(2)-1,1'-bis(diphenylphosphino)ferrocene)

Chemical Property of fac-W(CO)3(PMe3)(η(2)-1,1'-bis(diphenylphosphino)ferrocene)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of fac-W(CO)3(PMe3)(η(2)-1,1'-bis(diphenylphosphino)ferrocene)

There total 3 articles about fac-W(CO)3(PMe3)(η(2)-1,1'-bis(diphenylphosphino)ferrocene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

fac-W(CO)3(acetonitrile)(η(2)-1,1'-bis(diphenylphosphino)ferrocene) (163162-55-8) + trimethylphosphane (594-09-2) → fac-W(CO)3(PMe3)(η(2)-1,1'-bis(diphenylphosphino)ferrocene) (163162-57-0)

Guidance literature:

In dichloromethane; N2-atmosphere; excess PMe3, stirring at 25°C for 1 h (pptn.); decantation, washing (hexanes), drying (vac.); elem. anal.;

DOI:10.1016/0022-328X(95)05413-J

Reference yield: 89.0%

C39H31FeNO3P2W (163162-55-8) + trimethylphosphane (594-09-2) → fac-W(CO)3(PMe3)(η(2)-1,1'-bis(diphenylphosphino)ferrocene) (163162-57-0)

Guidance literature:

In dichloromethane; for 20h; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.poly.2014.01.023

Reference yield: 83.0%

[W(CO)3(C25H22P2)(C34H28FeP2)] + trimethylphosphane (594-09-2) → [W(CO)3(C25H22P2)(C34H28FeP2)] + fac-W(CO)3(PMe3)(η(2)-1,1'-bis(diphenylphosphino)ferrocene) (163162-57-0)

Guidance literature:

In 1,2-dichloro-ethane; (N2); stirring (room temp., 30 h); evapn. to dryness, TLC (SiO2; CH2Cl2/n-hexane);

DOI:10.1039/a704416j

upstream raw materials:

fac-W(CO)3(acetonitrile)(η(2)-1,1'-bis(diphenylphosphino)ferrocene)

trimethylphosphane

C₃₉H₃₁FeNO₃P₂W