[(1,3-[2,5-(i-Pr)2PhNC(=CH2)]2C6H4)U(μ-Cl)3][Li(THF)2]2

Base Information

Chemical Name:[(1,3-[2,5-(i-Pr)2PhNC(=CH2)]2C6H4)U(μ-Cl)3][Li(THF)2]2
CAS No.:1178556-59-6
Molecular Formula:C₅₀H₇₄Cl₃Li₂N₂O₄U
Molecular Weight:1125.42
Hs Code.:

Synonyms:[(1,3-[2,5-(i-Pr)2PhNC(=CH2)]2C6H4)U(μ-Cl)3][Li(THF)2]2

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Chemical Property of [(1,3-[2,5-(i-Pr)2PhNC(=CH2)]2C6H4)U(μ-Cl)3][Li(THF)2]2

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Technology Process of [(1,3-[2,5-(i-Pr)2PhNC(=CH2)]2C6H4)U(μ-Cl)3][Li(THF)2]2

There total 1 articles about [(1,3-[2,5-(i-Pr)2PhNC(=CH2)]2C6H4)U(μ-Cl)3][Li(THF)2]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1178556-83-6
UCl₄(THF)4

: [1,3-[2,5-(i-Pr)2PhNC(=CH₂)]2C₆H₄]Li₂(THF)4

: 1178556-59-6
[(1,3-[2,5-(i-Pr)2PhNC(=CH2)]2C6H4)U(μ-Cl)3][Li(THF)2]2

Guidance literature:: With potassium naphthalenide; In tetrahydrofuran; (Schlenk, inert atm.) a soln. of U-complex in THF was mixed at room temp. with a THF soln. of potassium naphthalenide, stirred for 20 min, a soln. of Li-compound in THF was added with vigorous stirring, the mixt. wasstirred for 2 h at room temp.; centrifuged, concd., layered with hexane, allowed to stand for 3 days atroom temp.; elem. anal.;
DOI:10.1021/ja9002525

Reference yield: 77.0%

: 1178556-59-6
[(1,3-[2,5-(i-Pr)2PhNC(=CH2)]2C6H4)U(μ-Cl)3][Li(THF)2]2

: 1178556-61-0
[(1,3-[2,5-(i-Pr)2PhNC(=CH2)]2C6H3)U(THF)(μ-Cl)2][Li(THF)2]

Guidance literature:: In tetrahydrofuran; (Schlenk, inert atm.) a soln. of U-complex in THF was placed in a glass high-pressure reactor and heated to 80°C in an oil bath for 6 h, cooled to room temp.; centrifuged, reduced in vol., layered with hexane, allowed to stand for 3 days;
DOI:10.1021/ja9002525