Technology Process of C36H40N4O7S2
There total 16 articles about C36H40N4O7S2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 10 steps
1: acetic acid; zinc / water / 1.83 h / 80 - 85 °C
2: glyoxylic acid ethyl ester; magnesium sulfate / dichloromethane / 0 - 20 °C
3: dmap; triethylamine / toluene / 18 h / 70 °C
4: ammonium cerium (IV) nitrate / water; acetonitrile / 0.25 h / -15 °C
5: dichloromethane / 4 h / 20 °C
6: copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine / 1,4-dioxane / 21 h / 100 °C
7: tetrabutyl ammonium fluoride / tetrahydrofuran; water / 0.33 h / 0 °C
8: hydrogen bromide; acetic acid / tetrahydrofuran / 0.5 h / 0 °C
9: tetrakis(triphenylphosphine) palladium(0); sodium ethanolate; caesium carbonate / 1,4-dioxane / 4 h / 100 °C
10: lithium borohydride / tetrahydrofuran / 0 - 20 °C
With
dmap; copper(l) iodide; lithium borohydride; tetrakis(triphenylphosphine) palladium(0); glyoxylic acid ethyl ester; ammonium cerium (IV) nitrate; tetrabutyl ammonium fluoride; hydrogen bromide; sodium ethanolate; magnesium sulfate; caesium carbonate; acetic acid; triethylamine; zinc;
In
tetrahydrofuran; 1,4-dioxane; dichloromethane; water; toluene; acetonitrile;
6: Sonogashira coupling / 9: Suzuki-Miyaura cross-coupling reaction;
DOI:10.1002/ejoc.201100242
- Guidance literature:
-
Multi-step reaction with 5 steps
1: copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine / 1,4-dioxane / 21 h / 100 °C
2: tetrabutyl ammonium fluoride / tetrahydrofuran; water / 0.33 h / 0 °C
3: hydrogen bromide; acetic acid / tetrahydrofuran / 0.5 h / 0 °C
4: tetrakis(triphenylphosphine) palladium(0); sodium ethanolate; caesium carbonate / 1,4-dioxane / 4 h / 100 °C
5: lithium borohydride / tetrahydrofuran / 0 - 20 °C
With
copper(l) iodide; lithium borohydride; tetrakis(triphenylphosphine) palladium(0); tetrabutyl ammonium fluoride; hydrogen bromide; sodium ethanolate; caesium carbonate; acetic acid; triethylamine;
In
tetrahydrofuran; 1,4-dioxane; water;
1: Sonogashira coupling / 4: Suzuki-Miyaura cross-coupling reaction;
DOI:10.1002/ejoc.201100242