((2S,5S,6R,8R)-8-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-5-(dimethyl(phenyl)silyl)-5,6,7,8-tetrahydro-2H-oxocine-2,6-diyl)bis-(methylene) diacetate

Base Information

Chemical Name:((2S,5S,6R,8R)-8-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-5-(dimethyl(phenyl)silyl)-5,6,7,8-tetrahydro-2H-oxocine-2,6-diyl)bis-(methylene) diacetate
CAS No.:1021603-67-7
Molecular Formula:C₃₅H₅₂O₇Si₂
Molecular Weight:640.965
Hs Code.:

((2S,5S,6R,8R)-8-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-5-(dimethyl(phenyl)silyl)-5,6,7,8-tetrahydro-2H-oxocine-2,6-diyl)bis-(methylene) diacetate

Synonyms:((2S,5S,6R,8R)-8-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-5-(dimethyl(phenyl)silyl)-5,6,7,8-tetrahydro-2H-oxocine-2,6-diyl)bis-(methylene) diacetate

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Chemical Property of ((2S,5S,6R,8R)-8-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-5-(dimethyl(phenyl)silyl)-5,6,7,8-tetrahydro-2H-oxocine-2,6-diyl)bis-(methylene) diacetate

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Technology Process of ((2S,5S,6R,8R)-8-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-5-(dimethyl(phenyl)silyl)-5,6,7,8-tetrahydro-2H-oxocine-2,6-diyl)bis-(methylene) diacetate

There total 1 articles about ((2S,5S,6R,8R)-8-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-5-(dimethyl(phenyl)silyl)-5,6,7,8-tetrahydro-2H-oxocine-2,6-diyl)bis-(methylene) diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1021603-74-6
C₃₁H₄₈O₅Si₂

: 108-24-7
acetic anhydride

: 1021603-67-7
((2S,5S,6R,8R)-8-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-5-(dimethyl(phenyl)silyl)-5,6,7,8-tetrahydro-2H-oxocine-2,6-diyl)bis-(methylene) diacetate

Guidance literature:: With dmap; triethylamine; In dichloromethane; for 1.5h; Cooling with ice;
DOI:10.1021/ol8003595

Reference yield:

: 1021603-67-7
((2S,5S,6R,8R)-8-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-5-(dimethyl(phenyl)silyl)-5,6,7,8-tetrahydro-2H-oxocine-2,6-diyl)bis-(methylene) diacetate

: C₂₁H₂₆O₇

Guidance literature:: ((2S,5S,6R,8R)-8-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-5-(dimethyl(phenyl)silyl)-5,6,7,8-tetrahydro-2H-oxocine-2,6-diyl)bis-(methylene) diacetate; With N-Bromosuccinimide; In tetrahydrofuran; at 0 - 20 ℃;

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃; for 0.333333h;
DOI:10.1021/ol8003595