5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-2-(tert-butoxycarbonylamino)-D-threo-L-galacto-decitose

Base Information

Chemical Name:5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-2-(tert-butoxycarbonylamino)-D-threo-L-galacto-decitose
CAS No.:236388-59-3
Molecular Formula:C₄₃H₅₁NO₈
Molecular Weight:709.88
Hs Code.:

Synonyms:5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-2-(tert-butoxycarbonylamino)-D-threo-L-galacto-decitose

Suppliers and Price of 5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-2-(tert-butoxycarbonylamino)-D-threo-L-galacto-decitose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-2-(tert-butoxycarbonylamino)-D-threo-L-galacto-decitose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-2-(tert-butoxycarbonylamino)-D-threo-L-galacto-decitose

There total 9 articles about 5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-2-(tert-butoxycarbonylamino)-D-threo-L-galacto-decitose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 144542-40-5
5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-2-(tert-butoxycarbonylamino)-D-threo-L-galacto-decitol

: 236388-59-3
5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-2-(tert-butoxycarbonylamino)-D-threo-L-galacto-decitose

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; In dichloromethane; at -78 - 0 ℃;
DOI:10.1021/jo990398l

Reference yield:

: 223526-25-8
(4S)-4-(2'-carboxyethyl)-2,2-dimethyloxazolidine-3-carboxylic acid tert-butyl ester

: 236388-59-3
5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-2-(tert-butoxycarbonylamino)-D-threo-L-galacto-decitose

Guidance literature:: Multi-step reaction with 6 steps

1.1: 88 percent / DCC; 4-DMAP

2.1: TiCl₄; TMEDA; PbCl₂

3.1: Grubbs ruthenium catalyst / 60 °C

3.2: BH₃*THF; NaOOH

4.1: 98 percent / NaH

5.1: p-TsOH / methanol

With dmap; N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride; sodium hydride; toluene-4-sulfonic acid; dicyclohexyl-carbodiimide; lead(II) chloride; Grubbs catalyst first generation; In methanol; 2.1: Takai methylenation / 3.1: ring closing metathesis / 6.1: Swern oxidation;
DOI:10.1016/j.tetlet.2004.07.163

Reference yield:

: 302800-64-2
3,4,6-tri-O-benzyl-1,2-dideoxy-D-lyxo-hex-1-enitol

: 236388-59-3
5,9-anhydro-6,7,8,10-tetra-O-benzyl-2,3,4-trideoxy-2-(tert-butoxycarbonylamino)-D-threo-L-galacto-decitose

Guidance literature:: Multi-step reaction with 6 steps

1.1: 88 percent / DCC; 4-DMAP

2.1: TiCl₄; TMEDA; PbCl₂

3.1: Grubbs ruthenium catalyst / 60 °C

3.2: BH₃*THF; NaOOH

4.1: 98 percent / NaH

5.1: p-TsOH / methanol

With dmap; N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride; sodium hydride; toluene-4-sulfonic acid; dicyclohexyl-carbodiimide; lead(II) chloride; Grubbs catalyst first generation; In methanol; 2.1: Takai methylenation / 3.1: ring closing metathesis / 6.1: Swern oxidation;
DOI:10.1016/j.tetlet.2004.07.163