bis(6-methylene-6'-methyl-2,2'-bipyridine)phenylphosphineoxide

Base Information

Chemical Name:bis(6-methylene-6'-methyl-2,2'-bipyridine)phenylphosphineoxide
CAS No.:371196-45-1
Molecular Formula:C₃₀H₂₇N₄OP
Molecular Weight:490.544
Hs Code.:

Synonyms:bis(6-methylene-6'-methyl-2,2'-bipyridine)phenylphosphineoxide

Suppliers and Price of bis(6-methylene-6'-methyl-2,2'-bipyridine)phenylphosphineoxide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(6-methylene-6'-methyl-2,2'-bipyridine)phenylphosphineoxide

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of bis(6-methylene-6'-methyl-2,2'-bipyridine)phenylphosphineoxide

There total 1 articles about bis(6-methylene-6'-methyl-2,2'-bipyridine)phenylphosphineoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 4411-80-7
6,6'-dimethyl-2,2'-bipyridine

: 644-97-3
Dichlorophenylphosphine

: 371196-45-1
bis(6-methylene-6'-methyl-2,2'-bipyridine)phenylphosphineoxide

Guidance literature:: 6,6'-dimethyl-2,2'-bipyridine; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 - 20 ℃;

Dichlorophenylphosphine; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 1h;

With sodium periodate; In dichloromethane; water; at 20 ℃;
DOI:10.1039/b102520c

Reference yield: 95.0%

: 371196-45-1
bis(6-methylene-6'-methyl-2,2'-bipyridine)phenylphosphineoxide

: 60790-54-7
[Cu(CH₃CN)4]⁽¹⁺⁾*BF₄^(1-)=[Cu(CH₃CN)4]BF₄

: 371196-50-8
[Cu(CH₃C₅H₃N(C₅H₃N)CH₂)2P(O)C₆H₅]⁽¹⁺⁾*BF₄^(1-)=[Cu(CH₃C₅H₃N(C₅H₃N)CH₂)2P(O)C₆H₅]BF₄

Guidance literature:: In dichloromethane; acetonitrile; under dry Ar, Schlenk setup; 1:1 mixt., ligand in CH2Cl2 added dropwise to soln. of copper complex, stirred for 2 h, evapd.; recrystd. (acetone/hexane), elem. anal.;
DOI:10.1039/b102520c

Reference yield: 65.0%

: 371196-45-1
bis(6-methylene-6'-methyl-2,2'-bipyridine)phenylphosphineoxide

: europium(III) nitrate hexahydrate

: Eu(bis(6-methylene-6'-methyl-2,2'-bipyridine)phenylphosphine oxide)(NO₃)3*6H₂O

Guidance literature:: In methanol; dichloromethane; soln. of the phosphine oxide in CH2Cl2 was added to soln. of Eu(NO3)3*6H2O in MeOH, stirred for 15 min; evapd. to dryness, dissolved in MeOH, Et2O was added, mother liquor decanted, ppt. washed with Et2O, dried under vac.; elem. anal.;
DOI:10.1021/ja0200847