Technology Process of C29H30O8
There total 20 articles about C29H30O8 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
tert.-butylhydroperoxide; tetrabutyl ammonium fluoride;
In
dimethyl sulfoxide;
for 1h;
Ambient temperature;
DOI:10.1055/s-1997-3271
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: 70 percent / TfOH / diethyl ether / 4 h / 0 - 25 °C
2.1: 95 percent / TBAF / tetrahydrofuran / 1.42 h / 0 - 25 °C
3.1: 82 percent / PDC; molecular sieves 3 Angstroem / CH2Cl2 / 2.33 h / 25 °C
4.1: LDA / tetrahydrofuran; hexane / 1 h / -78 °C
4.2: 66 percent / tetrahydrofuran; hexane / 0.33 h / -78 °C
5.1: TMSOTf / tetrahydrofuran / 1.67 h / 0 - 25 °C
6.1: TBHP; TBAF / dimethylsulfoxide; tetrahydrofuran / 0.5 h / 25 °C
With
tert.-butylhydroperoxide; dipyridinium dichromate; trifluorormethanesulfonic acid; trimethylsilyl trifluoromethanesulfonate; 3 A molecular sieve; tetrabutyl ammonium fluoride; lithium diisopropyl amide;
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane; dimethyl sulfoxide;
1.1: Etherification / 2.1: Silyl ether cleavage / 3.1: Oxidation / 4.1: Metallation / 4.2: Etherification / 5.1: Addition / 6.1: Epoxidation;
DOI:10.1055/s-2000-8223
- Guidance literature:
-
Multi-step reaction with 2 steps
1: TMSOTf / tetrahydrofuran / 1.67 h / 0 - 25 °C
2: TBHP; TBAF / dimethylsulfoxide; tetrahydrofuran / 0.5 h / 25 °C
With
tert.-butylhydroperoxide; trimethylsilyl trifluoromethanesulfonate; tetrabutyl ammonium fluoride;
In
tetrahydrofuran; dimethyl sulfoxide;
1: Addition / 2: Epoxidation;
DOI:10.1055/s-2000-8223
