Benzyloxyacetaldehyde diethyl acetal

Base Information

• Chemical Name: Benzyloxyacetaldehyde diethyl acetal
• CAS No.: 42783-78-8
• Molecular Formula: C13H20 O3
• Molecular Weight: 224.3
• Hs Code.: 2911000000
• European Community (EC) Number: 920-729-6,628-210-3
• DSSTox Substance ID: DTXSID40962698
• Nikkaji Number: J308.228H
• Wikidata: Q82944435
• Mol file: 42783-78-8.mol

Synonyms:Benzyloxyacetaldehyde diethyl acetal;42783-78-8;((2,2-Diethoxyethoxy)methyl)benzene;2,2-diethoxyethoxymethylbenzene;[(2,2-Diethoxyethoxy)methyl]benzene;MFCD00051786;1-BENZYLOXY-2,2-DIETHOXYETHANE;SCHEMBL1087301;DTXSID40962698;VTYTZCJKJNWMGA-UHFFFAOYSA-N;1,1-Diethoxy-2-(benzyloxy)ethane;(2,2-diethoxy-ethoxymethyl)-benzene;AKOS009159070;2-(benzyloxy)acetaldehyde diethyl acetal;AS-62449;Benzyloxyacetaldehyde diethyl acetal, 95%;CS-0299244;FT-0622856;D86369;EN300-202990;A872819;78314-63-3

Chemical Property of Benzyloxyacetaldehyde diethyl acetal

Chemical Property:

• Vapor Pressure: 0.00397mmHg at 25°C
• Refractive Index: n20/D 1.478(lit.)
• Boiling Point: 288.8°Cat760mmHg
• Flash Point: 110.9°C
• PSA: 27.69000
• Density: 1g/cm³
• LogP: 2.60230
• XLogP3: 2.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 8
• Exact Mass: 224.14124450
• Heavy Atom Count: 16
• Complexity: 149

Purity/Quality:

98%Min ^*data from raw suppliers

((2,2-Diethoxyethoxy)methyl)benzene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22
• Safety Statements: 26-37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCOC(COCC1=CC=CC=C1)OCC

Technology Process of Benzyloxyacetaldehyde diethyl acetal

There total 4 articles about Benzyloxyacetaldehyde diethyl acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.1%

→ benzyloxyacetaldehyde diethyl acetal (42783-78-8) + (benzoyloxy)acetaldehyde diethyl acetal (101268-52-4)

Guidance literature:

Reference yield: 70.0%

Bromoacetaldehyde diethyl acetal (2032-35-1) + benzyl alcohol (100-51-6,185532-71-2) → benzyloxyacetaldehyde diethyl acetal (42783-78-8)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; sodium hydride; Reflux;

DOI:10.1002/jlcr.1867

Reference yield:

Bromoacetaldehyde diethyl acetal (2032-35-1) → benzyloxyacetaldehyde diethyl acetal (42783-78-8)

Guidance literature:

With toluene;

DOI:10.1021/ja01628a108 DOI:10.1002/hlca.19500330647

upstream raw materials:

benzyl bromide

glycoaldehyde diethyl acetal

Bromoacetaldehyde diethyl acetal

benzyl alcohol

Downstream raw materials:

2-benzyloxy-1,1-bis-(4-hydroxy-2-oxo-2H-chromen-3-yl)-ethane

benzyloxyacetoaldehyde

glycoaldehyde diethyl acetal

1-Amino-2-hydroxyethane-P-methylphosphinic acid

Refernces

• 1、 -. "Process for Manufacture of Optically Active 2-(Acyloxymethyl)-1,3-Oxathiolanes". . . Retrieved 2010/06/19.
• 2、 Stuart, John G.,Nicholas, Kenneth M.. "COBALT-MEDIATED ALKYLATION OF SILOXY FURANS". . p. 949 - 963. Retrieved 2007/10/02.