Technology Process of 9-(3,4-bis(decyloxy)phenyl)-2,7-bis(chloromethyl)carbazole
There total 9 articles about 9-(3,4-bis(decyloxy)phenyl)-2,7-bis(chloromethyl)carbazole which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
methanesulfonyl chloride; triethylamine;
In
dichloromethane;
at 20 ℃;
for 48h;
DOI:10.1016/j.orgel.2010.03.024
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: hydrogenchloride; sodium nitrite / water / 2 h / 0 °C
1.2: 0 °C / pH 7
1.3: 0 - 20 °C
2.1: copper; potassium carbonate / N,N-dimethyl acetamide / 12 h / 160 °C / Inert atmosphere
3.1: sodium hydroxide / ethanol / 24 h / 110 °C
3.2: 3 h / 120 °C / pH < 7
4.1: sodium bis(2-methoxyethoxy)aluminium dihydride / benzene / 24 h / 100 °C
5.1: methanesulfonyl chloride; triethylamine / dichloromethane / 48 h / 20 °C
With
hydrogenchloride; copper; potassium carbonate; methanesulfonyl chloride; triethylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; sodium hydroxide; sodium nitrite;
In
ethanol; dichloromethane; N,N-dimethyl acetamide; water; benzene;
DOI:10.1016/j.orgel.2010.03.024
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: sodium hydroxide / ethanol / 24 h / 110 °C
1.2: 3 h / 120 °C / pH < 7
2.1: sodium bis(2-methoxyethoxy)aluminium dihydride / benzene / 24 h / 100 °C
3.1: methanesulfonyl chloride; triethylamine / dichloromethane / 48 h / 20 °C
With
methanesulfonyl chloride; triethylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; sodium hydroxide;
In
ethanol; dichloromethane; benzene;
DOI:10.1016/j.orgel.2010.03.024
