2-(2R,3S,4S,5S,6R)-3,5-dimethyl-(6-(E)-1-[2-((2R,4R,6R)-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-yl)methyl-(1,3-oxazol-4-yl)prop-1-en-2-yl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl)-ethanal

Base Information

Chemical Name:2-(2R,3S,4S,5S,6R)-3,5-dimethyl-(6-(E)-1-[2-((2R,4R,6R)-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-yl)methyl-(1,3-oxazol-4-yl)prop-1-en-2-yl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl)-ethanal
CAS No.:296784-96-8
Molecular Formula:C₅₃H₇₇NO₈Si₃
Molecular Weight:940.453
Hs Code.:

2-(2R,3S,4S,5S,6R)-3,5-dimethyl-(6-(E)-1-[2-((2R,4R,6R)-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-yl)methyl-(1,3-oxazol-4-yl)prop-1-en-2-yl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl)-ethanal

Synonyms:2-(2R,3S,4S,5S,6R)-3,5-dimethyl-(6-(E)-1-[2-((2R,4R,6R)-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-yl)methyl-(1,3-oxazol-4-yl)prop-1-en-2-yl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl)-ethanal

Suppliers and Price of 2-(2R,3S,4S,5S,6R)-3,5-dimethyl-(6-(E)-1-[2-((2R,4R,6R)-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-yl)methyl-(1,3-oxazol-4-yl)prop-1-en-2-yl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl)-ethanal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-(2R,3S,4S,5S,6R)-3,5-dimethyl-(6-(E)-1-[2-((2R,4R,6R)-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-yl)methyl-(1,3-oxazol-4-yl)prop-1-en-2-yl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl)-ethanal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-(2R,3S,4S,5S,6R)-3,5-dimethyl-(6-(E)-1-[2-((2R,4R,6R)-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-yl)methyl-(1,3-oxazol-4-yl)prop-1-en-2-yl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl)-ethanal

There total 4 articles about 2-(2R,3S,4S,5S,6R)-3,5-dimethyl-(6-(E)-1-[2-((2R,4R,6R)-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-yl)methyl-(1,3-oxazol-4-yl)prop-1-en-2-yl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl)-ethanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 296785-33-6
(2R,4R,6R)-2-[4-((E)-2-[(2R,3S,4S,5S,6R)-3,5-dimethyl-6-[2-(hydroxy)ethyl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl]prop-1-enyl)(1,3-oxazolyl-yl)]-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxymethyl)-tetrahydro-2H-pyran

: 296784-96-8
2-(2R,3S,4S,5S,6R)-3,5-dimethyl-(6-(E)-1-[2-((2R,4R,6R)-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-yl)methyl-(1,3-oxazol-4-yl)prop-1-en-2-yl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl)-ethanal

Guidance literature:: With pyridine; Dess-Martin periodane; In dichloromethane; at 20 ℃; for 0.333333h;
DOI:10.1021/ja002356g

Reference yield:

: (4R,6R)-2-[4-((E)-2-[(2R,3S,4S,5S,6R)-3,5-dimethyl-6-[2-(trimethylsilyloxy)ethyl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl]prop-1-enyl)(1,3-oxazol-2-yl)]-methyl-4-methoxy-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-ol

: 296784-96-8
2-(2R,3S,4S,5S,6R)-3,5-dimethyl-(6-(E)-1-[2-((2R,4R,6R)-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-yl)methyl-(1,3-oxazol-4-yl)prop-1-en-2-yl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl)-ethanal

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / diethyl ether; acetonitrile / 72 h / -50 °C

2: 467 mg / NaHCO₃ / methanol / 3.5 h / 20 °C

3: 100 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂ / 0.33 h / 20 °C

With pyridine; sodium hydrogencarbonate; Dess-Martin periodane; In methanol; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1021/ja002356g

Reference yield:

: 79271-56-0
triethylsilyl trifluoromethyl sulfonate

: 296784-96-8
2-(2R,3S,4S,5S,6R)-3,5-dimethyl-(6-(E)-1-[2-((2R,4R,6R)-4-methoxy-2-(triethylsilyloxy)-6-(triethylsilyloxy)methyl-tetrahydro-2H-pyran-2-yl)methyl-(1,3-oxazol-4-yl)prop-1-en-2-yl]-4-(triphenylsilyloxy)-tetrahydro-2H-pyran-2-yl)-ethanal

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / diethyl ether; acetonitrile / 72 h / -50 °C

2: 467 mg / NaHCO₃ / methanol / 3.5 h / 20 °C

3: 100 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂ / 0.33 h / 20 °C

With pyridine; sodium hydrogencarbonate; Dess-Martin periodane; In methanol; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1021/ja002356g