4-(methoxycarbonyl)benzenediazonium 4-methylbenzenesulfonate

Base Information

• Chemical Name: 4-(methoxycarbonyl)benzenediazonium 4-methylbenzenesulfonate
• CAS No.: 1228306-24-8
• Molecular Formula: C₇H₇O₃S*C₈H₇N₂O₂
• Molecular Weight: 334.353
• Mol file: 1228306-24-8.mol

Synonyms:4-(methoxycarbonyl)benzenediazonium 4-methylbenzenesulfonate

Chemical Property of 4-(methoxycarbonyl)benzenediazonium 4-methylbenzenesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 4-(methoxycarbonyl)benzenediazonium 4-methylbenzenesulfonate

There total 2 articles about 4-(methoxycarbonyl)benzenediazonium 4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

toluene-4-sulfonic acid (104-15-4) + 4-methoxycarbonyl aniline (619-45-4) → 4-(methoxycarbonyl)benzenediazonium 4-methylbenzenesulfonate (1228306-24-8)

Guidance literature:

toluene-4-sulfonic acid; 4-methoxycarbonyl aniline; With acetic acid; In tetrahydrofuran; for 0.0833333h; Cooling with ice;

With tert.-butylnitrite; In tetrahydrofuran; at 0 - 20 ℃; for 1.16667h;

DOI:10.1055/s-0039-1690159

Reference yield:

C7H8O3S*C8H9NO2 (1155358-63-6) → 4-(methoxycarbonyl)benzenediazonium 4-methylbenzenesulfonate (1228306-24-8)

Guidance literature:

With tert.-butylnitrite; In tetrahydrofuran; at -10 - 20 ℃;

DOI:10.1055/s-0029-1219090

Reference yield: 92.0%

4-(methoxycarbonyl)benzenediazonium 4-methylbenzenesulfonate (1228306-24-8) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → methyl (E)-4-(3-methoxy-3-oxoprop-1-en-1-yl)benzoate (52148-89-7)

Guidance literature:

With palladium diacetate; In water; at 75 ℃; for 0.0166667h; Microwave irradiation; Green chemistry;

DOI:10.3762/bjoc.11.41

upstream raw materials:

C₇H₈O₃S*C₈H₉NO₂

toluene-4-sulfonic acid

4-methoxycarbonyl aniline

Downstream raw materials:

methyl 4-(triethoxysilyl)benzoate

methyl (E)-4-(3-methoxy-3-oxoprop-1-en-1-yl)benzoate

(E)-methyl 4-styrylbenzoate