5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diylbis(trifluoromethanesulfonate)

Base Information

• Chemical Name: 5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diylbis(trifluoromethanesulfonate)
• CAS No.: 1421045-35-3
• Molecular Formula: C₈₀H₅₆F₆O₆S₂
• Molecular Weight: 1291.44
• Mol file: 1421045-35-3.mol

Synonyms:5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diylbis(trifluoromethanesulfonate)

Chemical Property of 5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diylbis(trifluoromethanesulfonate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diylbis(trifluoromethanesulfonate)

There total 1 articles about 5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diylbis(trifluoromethanesulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

trifluoromethylsulfonic anhydride (358-23-6) + 5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diol (1374751-49-1) → 5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diylbis(trifluoromethanesulfonate) (1421045-35-3)

Guidance literature:

With pyridine; In dichloromethane; at 20 ℃; for 3.01667h; Inert atmosphere;

DOI:10.1002/asia.201200723

Reference yield: 97.0%

3,3-Dimethylbut-1-yne (917-92-0) + 5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diylbis(trifluoromethanesulfonate) (1421045-35-3) → 2,11-bis(3,3-dimethylbut-1-yn-1-yl)-5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene (1421045-37-5)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; water; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1002/asia.201200723

Reference yield: 86.0%

5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diylbis(trifluoromethanesulfonate) (1421045-35-3) + 2,4,6-trimethylaniline (88-05-1) → N2,N11,5,8,14,17-hexamesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diamine (1421045-38-6)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; caesium carbonate; In toluene; at 20 ℃; for 24h; Inert atmosphere; Reflux;

DOI:10.1002/asia.201200723

upstream raw materials:

trifluoromethylsulfonic anhydride

5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diol

Downstream raw materials:

2,11-bis(3,3-dimethylbut-1-yn-1-yl)-5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene

N₂,N₁₁,5,8,14,17-hexamesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-diamine

5,8,14,17-tetramesitylhexabenzo[bc,ef,hi,kl,no,qr]coronene-2,11-dicarbonitrile