Allyl-{(R)-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-tridecyl}-carbamic acid tert-butyl ester

Base Information

Chemical Name:Allyl-{(R)-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-tridecyl}-carbamic acid tert-butyl ester
CAS No.:197707-20-3
Molecular Formula:C₄₀H₆₅NO₃Si
Molecular Weight:636.047
Hs Code.:

Synonyms:Allyl-{(R)-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-tridecyl}-carbamic acid tert-butyl ester

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Chemical Property of Allyl-{(R)-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-tridecyl}-carbamic acid tert-butyl ester

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Technology Process of Allyl-{(R)-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-tridecyl}-carbamic acid tert-butyl ester

There total 7 articles about Allyl-{(R)-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-tridecyl}-carbamic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 106-95-6
allyl bromide

: 197707-19-0
{(R)-1-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-tridecyl}-carbamic acid tert-butyl ester

: 197707-20-3
Allyl-{(R)-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-tridecyl}-carbamic acid tert-butyl ester

Guidance literature:: With potassium hydride; In tetrahydrofuran; at 0 - 20 ℃; for 3h;
DOI:10.1016/S0957-4166(97)00563-6

Reference yield:

: 136923-04-1
tert-butyl (4S)-4-(3-hydroxypropyl)-2,2-dimethyl-1,3-oxazolidine-3-carboxylate

: 197707-20-3
Allyl-{(R)-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-tridecyl}-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 100 percent / imidazole / CH₂Cl₂ / Ambient temperature

2: 98 percent / PdCl₂(CH₃CN)2 / acetonitrile / Heating

3: 97 percent / Et₃N, DMAP / CH₂Cl₂ / Ambient temperature

4: 85 percent / CuI / diethyl ether / -35 °C

5: 92 percent / KH / tetrahydrofuran / 0 deg C to RT

With 1H-imidazole; dmap; dichloro bis(acetonitrile) palladium(II); copper(l) iodide; potassium hydride; triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1016/S0040-4039(97)01759-0

Reference yield:

: 98499-04-8
Undecyllithium

: 197707-20-3
Allyl-{(R)-1-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-tridecyl}-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / CuI / diethyl ether / -35 °C

2: 92 percent / KH / tetrahydrofuran / 0 deg C to RT

With copper(l) iodide; potassium hydride; In tetrahydrofuran; diethyl ether;
DOI:10.1016/S0040-4039(97)01759-0