1-benzyl-1H-[1,2,4]triazol-4-ium-4-methylbenzoyl-2,4,6-trinitrophenylmethylide

Base Information

• Chemical Name: 1-benzyl-1H-[1,2,4]triazol-4-ium-4-methylbenzoyl-2,4,6-trinitrophenylmethylide
• CAS No.: 263152-05-2
• Molecular Formula: C₂₄H₁₈N₆O₇
• Molecular Weight: 502.443
• Mol file: 263152-05-2.mol

Synonyms:1-benzyl-1H-[1,2,4]triazol-4-ium-4-methylbenzoyl-2,4,6-trinitrophenylmethylide

Chemical Property of 1-benzyl-1H-[1,2,4]triazol-4-ium-4-methylbenzoyl-2,4,6-trinitrophenylmethylide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-benzyl-1H-[1,2,4]triazol-4-ium-4-methylbenzoyl-2,4,6-trinitrophenylmethylide

There total 3 articles about 1-benzyl-1H-[1,2,4]triazol-4-ium-4-methylbenzoyl-2,4,6-trinitrophenylmethylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

2,4,6-trinitrochlorobenzene (88-88-0) + 1-benzyl-4-(4-methyl)phenacyl-1H-[1,2,4]triazol-4-ium bromide → 1-benzyl-1H-[1,2,4]triazol-4-ium-4-methylbenzoyl-2,4,6-trinitrophenylmethylide (263152-05-2)

Guidance literature:

With triethylamine; In chloroform; at 0 - 20 ℃; for 3h;

DOI:10.1016/S0040-4020(99)01006-6

Reference yield:

1-benzyl-1,2,4-triazole (6085-94-5) → 1-benzyl-1H-[1,2,4]triazol-4-ium-4-methylbenzoyl-2,4,6-trinitrophenylmethylide (263152-05-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 75 percent / acetone / 8 h / Heating

2: 62 percent / Et₃N / CHCl₃ / 3 h / 0 - 20 °C

With triethylamine; In chloroform; acetone; 1: Addition / 2: Arylation;

DOI:10.1016/S0040-4020(99)01006-6

Reference yield:

4-(bromoacetyl)toluene (619-41-0) → 1-benzyl-1H-[1,2,4]triazol-4-ium-4-methylbenzoyl-2,4,6-trinitrophenylmethylide (263152-05-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 75 percent / acetone / 8 h / Heating

2: 62 percent / Et₃N / CHCl₃ / 3 h / 0 - 20 °C

With triethylamine; In chloroform; acetone; 1: Addition / 2: Arylation;

DOI:10.1016/S0040-4020(99)01006-6

upstream raw materials:

2,4,6-trinitrochlorobenzene

1-benzyl-1,2,4-triazole

4-(bromoacetyl)toluene