2-Benzyl-1,2,3,4,4a,9-hexahydro-cis-13bH-9,13b-methanodibenzo<3,4;6,7>cyclohepta<1,2-c>pyridine

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Chemical Name:2-Benzyl-1,2,3,4,4a,9-hexahydro-cis-13bH-9,13b-methanodibenzo<3,4;6,7>cyclohepta<1,2-c>pyridine
CAS No.:72917-21-6
Molecular Formula:C₂₆H₂₅N
Molecular Weight:351.491
Hs Code.:

Synonyms:2-Benzyl-1,2,3,4,4a,9-hexahydro-cis-13bH-9,13b-methanodibenzo<3,4;6,7>cyclohepta<1,2-c>pyridine

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Chemical Property of 2-Benzyl-1,2,3,4,4a,9-hexahydro-cis-13bH-9,13b-methanodibenzo<3,4;6,7>cyclohepta<1,2-c>pyridine

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Technology Process of 2-Benzyl-1,2,3,4,4a,9-hexahydro-cis-13bH-9,13b-methanodibenzo<3,4;6,7>cyclohepta<1,2-c>pyridine

There total 4 articles about 2-Benzyl-1,2,3,4,4a,9-hexahydro-cis-13bH-9,13b-methanodibenzo<3,4;6,7>cyclohepta<1,2-c>pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 72917-20-5
2-Benzyl-1,2,4a,9-tetrahydro-cis-13bH-9,13b-methanodibenzo<3,4;6,7>cyclohepta<1,2-c>pyridin-3(4H)-one

: 72917-21-6
2-Benzyl-1,2,3,4,4a,9-hexahydro-cis-13bH-9,13b-methanodibenzo<3,4;6,7>cyclohepta<1,2-c>pyridine

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; for 4h; Heating;
DOI:10.1021/jo01296a032

Reference yield:

: 1197-51-9
N-propargylbenzylamine

: 72917-21-6
2-Benzyl-1,2,3,4,4a,9-hexahydro-cis-13bH-9,13b-methanodibenzo<3,4;6,7>cyclohepta<1,2-c>pyridine

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) THF, pyridine, RT, 3 h, 2.) p-xylene, reflux, 90 min

2: 30.5 percent / p-Toluenesulfonic acid / acetic acid / 26 h / Heating

3: 10percent Pd/C, H₂ / tetrahydrofuran; acetic acid / 84 h / 2585.7 Torr / Parr shaker

4: 63 percent / LiAlH₄ / tetrahydrofuran / 4 h / Heating

With palladium on activated charcoal; lithium aluminium tetrahydride; hydrogen; toluene-4-sulfonic acid; In tetrahydrofuran; acetic acid;
DOI:10.1021/jo01296a032

Reference yield:

: 72917-19-2
2-Benzyl-1,2-dihydro-13bH-9,13b-methanodibenzo<3,4;6,7>cyclohepta<1,2-c>pyridin-3(9H)-one

: 72917-21-6
2-Benzyl-1,2,3,4,4a,9-hexahydro-cis-13bH-9,13b-methanodibenzo<3,4;6,7>cyclohepta<1,2-c>pyridine

Guidance literature:: Multi-step reaction with 2 steps

1: 10percent Pd/C, H₂ / tetrahydrofuran; acetic acid / 84 h / 2585.7 Torr / Parr shaker

2: 63 percent / LiAlH₄ / tetrahydrofuran / 4 h / Heating

With palladium on activated charcoal; lithium aluminium tetrahydride; hydrogen; In tetrahydrofuran; acetic acid;
DOI:10.1021/jo01296a032