Benzoic acid (Z)-(S)-9-(tert-butyl-diphenyl-silanyloxy)-10-oxo-dec-6-enyl ester

Base Information

Chemical Name:Benzoic acid (Z)-(S)-9-(tert-butyl-diphenyl-silanyloxy)-10-oxo-dec-6-enyl ester
CAS No.:100311-73-7
Molecular Formula:C₃₃H₄₀O₄Si
Molecular Weight:528.764
Hs Code.:

Synonyms:Benzoic acid (Z)-(S)-9-(tert-butyl-diphenyl-silanyloxy)-10-oxo-dec-6-enyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzoic acid (Z)-(S)-9-(tert-butyl-diphenyl-silanyloxy)-10-oxo-dec-6-enyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of Benzoic acid (Z)-(S)-9-(tert-butyl-diphenyl-silanyloxy)-10-oxo-dec-6-enyl ester

There total 9 articles about Benzoic acid (Z)-(S)-9-(tert-butyl-diphenyl-silanyloxy)-10-oxo-dec-6-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 53036-80-9
6-carboxy hexylidene triphenylphosphorane

: 100311-73-7
Benzoic acid (Z)-(S)-9-(tert-butyl-diphenyl-silanyloxy)-10-oxo-dec-6-enyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: lithium hexamethyldisilazane (LiHMDS) / tetrahydrofuran; hexamethylphosphoric acid triamide / 2.5 h / -78 - 20 °C

2: NaHCO₃ / tetrahydrofuran; hexamethylphosphoric acid triamide / 2 h / Ambient temperature

3: 68 percent / AlH₃*Et₂O / tetrahydrofuran / 0.5 h / 0 °C

4: 85 percent / Et₃N / CH₂Cl₂ / 0 °C

5: aq. TFA / tetrahydrofuran / Ambient temperature

6: Na₂CO₃, Pb(OAc)4 / CH₂Cl₂ / 0.25 h / -78 °C

With lead(IV) acetate; aluminium hydride * diethyl ether; sodium hydrogencarbonate; sodium carbonate; triethylamine; trifluoroacetic acid; lithium hexamethyldisilazane; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane;
DOI:10.1021/jo00356a004

Reference yield:

: 100311-72-6
Benzoic acid (Z)-(9S,10R)-9-(tert-butyl-diphenyl-silanyloxy)-10,11-dihydroxy-undec-6-enyl ester

: 100311-73-7
Benzoic acid (Z)-(S)-9-(tert-butyl-diphenyl-silanyloxy)-10-oxo-dec-6-enyl ester

Guidance literature:: With lead(IV) acetate; sodium carbonate; In dichloromethane; at -78 ℃; for 0.25h;
DOI:10.1021/jo00356a004

Reference yield:

: 618-32-6
Benzoyl bromide

: 100311-73-7
Benzoic acid (Z)-(S)-9-(tert-butyl-diphenyl-silanyloxy)-10-oxo-dec-6-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / Et₃N / CH₂Cl₂ / 0 °C

2: aq. TFA / tetrahydrofuran / Ambient temperature

3: Na₂CO₃, Pb(OAc)4 / CH₂Cl₂ / 0.25 h / -78 °C

With lead(IV) acetate; sodium carbonate; triethylamine; trifluoroacetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00356a004