diethyl {3-[1-(diethoxyphosphinyl)-2-ethoxy-2-oxoethoxy]-5-(ethoxycarbonyl)-2-hydroxyphenyl}hydroxypropanedioate

Base Information

Chemical Name:diethyl {3-[1-(diethoxyphosphinyl)-2-ethoxy-2-oxoethoxy]-5-(ethoxycarbonyl)-2-hydroxyphenyl}hydroxypropanedioate
CAS No.:188564-70-7
Molecular Formula:C₂₄H₃₅O₁₄P
Molecular Weight:578.507
Hs Code.:

Synonyms:diethyl {3-[1-(diethoxyphosphinyl)-2-ethoxy-2-oxoethoxy]-5-(ethoxycarbonyl)-2-hydroxyphenyl}hydroxypropanedioate

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Chemical Property of diethyl {3-[1-(diethoxyphosphinyl)-2-ethoxy-2-oxoethoxy]-5-(ethoxycarbonyl)-2-hydroxyphenyl}hydroxypropanedioate

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Technology Process of diethyl {3-[1-(diethoxyphosphinyl)-2-ethoxy-2-oxoethoxy]-5-(ethoxycarbonyl)-2-hydroxyphenyl}hydroxypropanedioate

There total 3 articles about diethyl {3-[1-(diethoxyphosphinyl)-2-ethoxy-2-oxoethoxy]-5-(ethoxycarbonyl)-2-hydroxyphenyl}hydroxypropanedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 188564-69-4
ethyl 3-[1-(diethoxyphosphinyl)-2-ethoxy-2-oxoethoxy]-4-hydroxybenzoate

: 609-09-6
Diethyl ketomalonate

: 188564-70-7
diethyl {3-[1-(diethoxyphosphinyl)-2-ethoxy-2-oxoethoxy]-5-(ethoxycarbonyl)-2-hydroxyphenyl}hydroxypropanedioate

Guidance literature:: With tin(IV) chloride; In dichloromethane; at 20 ℃; for 36h;
DOI:10.1016/S0968-0896(96)00239-8

Reference yield:

: 17507-56-1
ethyl 2-diazo-2-(diethoxyphosphoryl)acetate

: 188564-70-7
diethyl {3-[1-(diethoxyphosphinyl)-2-ethoxy-2-oxoethoxy]-5-(ethoxycarbonyl)-2-hydroxyphenyl}hydroxypropanedioate

Guidance literature:: Multi-step reaction with 3 steps

1: 68 percent / rhodium(II) diacetate / benzene / Heating

2: 95 percent / H₂ / 10percent Pd/C / ethanol / 2 h

3: 30 percent / SnCl₄ / CH₂Cl₂ / 36 h / 20 °C

With rhodium(II) acetate; hydrogen; tin(IV) chloride; palladium on activated charcoal; In ethanol; dichloromethane; benzene;
DOI:10.1016/S0968-0896(96)00239-8

Reference yield:

: 177429-27-5
ethyl 4-benzyloxy-3-hydroxybenzoate

: 188564-70-7
diethyl {3-[1-(diethoxyphosphinyl)-2-ethoxy-2-oxoethoxy]-5-(ethoxycarbonyl)-2-hydroxyphenyl}hydroxypropanedioate

Guidance literature:: Multi-step reaction with 3 steps

1: 68 percent / rhodium(II) diacetate / benzene / Heating

2: 95 percent / H₂ / 10percent Pd/C / ethanol / 2 h

3: 30 percent / SnCl₄ / CH₂Cl₂ / 36 h / 20 °C

With rhodium(II) acetate; hydrogen; tin(IV) chloride; palladium on activated charcoal; In ethanol; dichloromethane; benzene;
DOI:10.1016/S0968-0896(96)00239-8