6-(trifluoroacetamido)hexyl 2-acetamido-2-deoxy-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-β-D-glucopyranoside

Base Information

Chemical Name:6-(trifluoroacetamido)hexyl 2-acetamido-2-deoxy-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-β-D-glucopyranoside
CAS No.:78489-56-2
Molecular Formula:C₄₃H₅₅F₃N₂O₁₁
Molecular Weight:832.912
Hs Code.:

Synonyms:6-(trifluoroacetamido)hexyl 2-acetamido-2-deoxy-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-β-D-glucopyranoside

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Chemical Property of 6-(trifluoroacetamido)hexyl 2-acetamido-2-deoxy-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-β-D-glucopyranoside

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Technology Process of 6-(trifluoroacetamido)hexyl 2-acetamido-2-deoxy-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-β-D-glucopyranoside

There total 6 articles about 6-(trifluoroacetamido)hexyl 2-acetamido-2-deoxy-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 78489-55-1
6-(trifluoroacetamido)hexyl 2-acetamido-2-deoxy-4,6-O-(p-methoxybenzylidene)-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-β-D-glucopyranoside

: 162118-38-9
(3S,4R,5R,6S)-3,4,5-tris(benzyloxy)-6-methyltetrahydro-2H-pyran-2-ol

: 78489-56-2
6-(trifluoroacetamido)hexyl 2-acetamido-2-deoxy-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-β-D-glucopyranoside

Guidance literature:: With acetic acid; at 100 ℃; for 0.333333h;
DOI:10.1016/S0008-6215(00)86027-9

Reference yield:

: 40248-35-9
6-(trifluoroacetamido)hexyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside

: 78489-56-2
6-(trifluoroacetamido)hexyl 2-acetamido-2-deoxy-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 85 percent / sodium methoxyde / methanol / 3 h / Ambient temperature

2: 78 percent / zinc chloride / 48 h / Ambient temperature

3: 1.) tetraethylammonium bromide / 1.) dichloromethane, 2 h, r.t; 2.) dichloromethane, HCONMe₂, 5 d, r.t.

4: 81 percent / 80percent acetic acid / 0.33 h / 100 °C

With sodium methylate; acetic acid; zinc(II) chloride; tetraethylammonium bromide; In methanol;
DOI:10.1016/S0008-6215(00)86027-9

Reference yield:

: 40248-34-8
6-trifluoroacetamido-1-hexanol

: 78489-56-2
6-(trifluoroacetamido)hexyl 2-acetamido-2-deoxy-3-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 60 percent / p-toluenesulfonic acid / toluene; nitromethane / 2 h / Heating

2: 85 percent / sodium methoxyde / methanol / 3 h / Ambient temperature

3: 78 percent / zinc chloride / 48 h / Ambient temperature

4: 1.) tetraethylammonium bromide / 1.) dichloromethane, 2 h, r.t; 2.) dichloromethane, HCONMe₂, 5 d, r.t.

5: 81 percent / 80percent acetic acid / 0.33 h / 100 °C

With sodium methylate; toluene-4-sulfonic acid; acetic acid; zinc(II) chloride; tetraethylammonium bromide; In methanol; nitromethane; toluene;
DOI:10.1016/S0008-6215(00)86027-9