1,4-Methanonaphthalene-5-carbonitrile,1,4,4a,5,8,8a-hexahydro-5-methyl-8-oxo-,(1R,4S,4aR,5R,8aS)-rel-(9CI)

Base Information

Chemical Name:1,4-Methanonaphthalene-5-carbonitrile,1,4,4a,5,8,8a-hexahydro-5-methyl-8-oxo-,(1R,4S,4aR,5R,8aS)-rel-(9CI)
CAS No.:828248-62-0
Molecular Formula:C₁₃H₁₃NO
Molecular Weight:199.252
Hs Code.:
Mol file:828248-62-0.mol

Synonyms:1,4-Methanonaphthalene-5-carbonitrile,1,4,4a,5,8,8a-hexahydro-5-methyl-8-oxo-,(1R,4S,4aR,5R,8aS)-rel-(9CI)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,4-Methanonaphthalene-5-carbonitrile,1,4,4a,5,8,8a-hexahydro-5-methyl-8-oxo-,(1R,4S,4aR,5R,8aS)-rel-(9CI)

Chemical Property:

Boiling Point:367.9±42.0 °C(Predicted)
PSA：40.86000
Density:1.19±0.1 g/cm3(Predicted)
LogP:2.09348

Purity/Quality:

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Technology Process of 1,4-Methanonaphthalene-5-carbonitrile,1,4,4a,5,8,8a-hexahydro-5-methyl-8-oxo-,(1R,4S,4aR,5R,8aS)-rel-(9CI)

There total 4 articles about 1,4-Methanonaphthalene-5-carbonitrile,1,4,4a,5,8,8a-hexahydro-5-methyl-8-oxo-,(1R,4S,4aR,5R,8aS)-rel-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 134837-20-0
1-methyl-4-oxocyclohexa-2,5-dienecarbonitrile

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 828248-61-9,828248-62-0
(1S,4R,4aS,5R,8aR)-5-methyl-8-oxo-1,4,4a,5,8,8a-hexahydro-1,4-methanonaphthalene-5-carbonitrile

: 828248-61-9,828248-62-0
5-methyl-8-oxo-1,4,4a,5,8,8a-hexahydro-1,4-methanonaphthalene-5-carbonitrile

Guidance literature:: With (R)-3,3'-di(anthracen-9-yl)-5,5',6,6',7,7',8,8'-octahydro-[1,1'-binaphthalene]-2,2'-diyl hydrogen phosphate; sodium sulfate; In dichloromethane; o-xylene; at -10 ℃; for 48h; Overall yield = 93 %; enantioselective reaction;
DOI:10.1039/c5ob01760b

Reference yield:

: 134837-20-0
1-methyl-4-oxocyclohexa-2,5-dienecarbonitrile

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 828248-61-9,828248-62-0
(1S,4R,4aS,5R,8aR)-5-methyl-8-oxo-1,4,4a,5,8,8a-hexahydro-1,4-methanonaphthalene-5-carbonitrile

: 828248-61-9,828248-62-0
5-methyl-8-oxo-1,4,4a,5,8,8a-hexahydro-1,4-methanonaphthalene-5-carbonitrile

Guidance literature:: With (R)-3,3'-di(anthracen-9-yl)-5,5',6,6',7,7',8,8'-octahydro-[1,1'-binaphthalene]-2,2'-diyl hydrogen phosphate; sodium sulfate; In dichloromethane; o-xylene; at -10 ℃; for 48h; Overall yield = 93 %; enantioselective reaction;
DOI:10.1039/c5ob01760b