1,5-bis[(4-hexylphenyl)methyl]-2,3,6,7-tetraphenylbenzo[1,2-b:4,5-b']dipyrrole

Base Information

Chemical Name:1,5-bis[(4-hexylphenyl)methyl]-2,3,6,7-tetraphenylbenzo[1,2-b:4,5-b']dipyrrole
CAS No.:1240041-79-5
Molecular Formula:C₆₀H₆₀N₂
Molecular Weight:809.15
Hs Code.:

Synonyms:1,5-bis[(4-hexylphenyl)methyl]-2,3,6,7-tetraphenylbenzo[1,2-b:4,5-b']dipyrrole

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Chemical Property of 1,5-bis[(4-hexylphenyl)methyl]-2,3,6,7-tetraphenylbenzo[1,2-b:4,5-b']dipyrrole

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Technology Process of 1,5-bis[(4-hexylphenyl)methyl]-2,3,6,7-tetraphenylbenzo[1,2-b:4,5-b']dipyrrole

There total 1 articles about 1,5-bis[(4-hexylphenyl)methyl]-2,3,6,7-tetraphenylbenzo[1,2-b:4,5-b']dipyrrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 591-50-4
iodobenzene

: 1210480-98-0
N,N'-bis[(4-hexylphenyl)methyl]-2,5-bis(phenylethynyl)benzene-1,4-diamine

: 1240041-79-5
1,5-bis[(4-hexylphenyl)methyl]-2,3,6,7-tetraphenylbenzo[1,2-b:4,5-b']dipyrrole

Guidance literature:: N,N'-bis[(4-hexylphenyl)methyl]-2,5-bis(phenylethynyl)benzene-1,4-diamine; With n-butyllithium; In tetrahydrofuran; hexane; at 0 - 20 ℃; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; hexane; toluene; at 120 ℃; for 3h; Inert atmosphere;

iodobenzene; With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; tri-tert-butyl phosphine; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 18h; Inert atmosphere;
DOI:10.1002/asia.200800471

Reference yield: 70.0%

: 1240041-79-5
1,5-bis[(4-hexylphenyl)methyl]-2,3,6,7-tetraphenylbenzo[1,2-b:4,5-b']dipyrrole

: 121976-97-4
2,3,6,7-tetraphenylbenzo[1,2-b:4,5-b’]dipyrrole

Guidance literature:: With aluminum (III) chloride; methoxybenzene; at 100 - 120 ℃; for 12h;
DOI:10.3987/COM-14-S(K)16

Reference yield:

: 1240041-79-5
1,5-bis[(4-hexylphenyl)methyl]-2,3,6,7-tetraphenylbenzo[1,2-b:4,5-b']dipyrrole

: 1,2,3,5,6,7-hexaphenylbenzo-[1,2-b:4,5-b']dipyrrole

Guidance literature:: Multi-step reaction with 2 steps

1: aluminum (III) chloride; methoxybenzene / 12 h / 100 - 120 °C

2: tri-tert-butyl phosphine; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium t-butanolate / toluene / 24 h / 120 °C

With aluminum (III) chloride; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; tri-tert-butyl phosphine; methoxybenzene; sodium t-butanolate; In toluene;
DOI:10.3987/COM-14-S(K)16