C₈₀H₁₂₃NO₁₃Si₂

Base Information

Chemical Name:C₈₀H₁₂₃NO₁₃Si₂
CAS No.:148933-91-9
Molecular Formula:C₈₀H₁₂₃NO₁₃Si₂
Molecular Weight:1363.03
Hs Code.:

C<sub>80</sub>H<sub>123</sub>NO<sub>13</sub>Si<sub>2</sub>

Synonyms:C₈₀H₁₂₃NO₁₃Si₂

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Chemical Property of C₈₀H₁₂₃NO₁₃Si₂

Chemical Property:

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Technology Process of C₈₀H₁₂₃NO₁₃Si₂

There total 51 articles about C₈₀H₁₂₃NO₁₃Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₈₁H₁₂₇NO₁₄Si₂

: 148933-91-9
C₈₀H₁₂₃NO₁₃Si₂

Guidance literature:: With lead(IV) acetate; sodium carbonate; In benzene; at 0 - 25 ℃; for 0.25h; Yield given;
DOI:10.1039/c39930000619

Reference yield:

: 148933-83-9
(1R,2R,3R)-2-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-cyclohexanol

: 148933-91-9
C₈₀H₁₂₃NO₁₃Si₂

Guidance literature:: Multi-step reaction with 19 steps

1: 1.) (COCl)2, DMSO, 2.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 1 h, 2.) r.t., 2 h

2: LDA / tetrahydrofuran; hexane / 1.) -78 deg C, 15 min, 2.) 25 deg C, 2 h

3: Pd(OAc)2 / acetonitrile / 24 h / 50 °C

4: 95 percent / LiBH₄, CeCl₃*7H₂O / tetrahydrofuran; methanol / 1 h / -78 °C

5: 2.) LiEt₃BH / 1.) xylene, reflux, 48 h, 2.) THF, r.t., 2 h

6: 100 percent / H₂ / 10percent Pd/C / ethanol / 16 h / 25 °C

7: 1.) o-O₂NC₆H₄SeCN, n-Bu₃P, 2.) 30percent aq. H₂O₂ / 1.) THF, 25 deg C, 3 h, 2.) THF, 25 deg C, 6 h

8: 1.) O₃, 2.) Me₂S / 1.) CH₂Cl₂, MeOH, -78 deg C, 2.) 25 deg C, overnight

9: 95 percent / LiCl, (i-Pr)2NEt / acetonitrile / 1.) 25 deg C, 15 min, 2.) 25 deg C, 6 h

10: Et₃SiH / Rh(PPh₃)3Cl / 2 h / 50 °C

11: 49percent aq. HF / acetonitrile / 3 h / 25 °C

12: imidazole / dimethylformamide / 16 h / 25 °C

14: 98 percent / aq. LiBH₄ / diethyl ether; tetrahydrofuran / 1 h / 25 °C

15: 91 percent / Et₃N, DMAP / CH₂Cl₂ / 24 h / 25 °C

16: 91 percent / LiEt₃BH / tetrahydrofuran / 2.5 h / 25 °C

17: 85 percent / 4-pyrrolidinopyridine, (i-Pr)2NEt, 1,3-diisopropylcarbodiimide / CH₂Cl₂ / 24 h / -20 °C

18: aq. 4-methylmorpholine-N-oxide, OsO₄ / acetone / 16 h / 25 °C

19: Pb(OAc)4, Na₂CO₃ / benzene / 1.5 h / 25 °C

With 1H-imidazole; lead(IV) acetate; triethylsilane; dmap; palladium diacetate; osmium(VIII) oxide; lithium borohydride; ortho-nitrophenyl selenocyanate; cerium(III) chloride; oxalyl dichloride; dimethylsulfide; tributylphosphine; hydrogen fluoride; hydrogen; dihydrogen peroxide; lithium triethylborohydride; sodium carbonate; 4-pyrrolidin-1-ylpyridine; ozone; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; lithium chloride; diisopropyl-carbodiimide; lithium diisopropyl amide; palladium on activated charcoal; Wilkinson's catalyst; In tetrahydrofuran; methanol; diethyl ether; ethanol; hexane; dichloromethane; N,N-dimethyl-formamide; acetone; acetonitrile; benzene;

Reference yield:

: 128209-97-2
(1R,3R,4R)-4-[(tert-butyldimethylsilyl)oxy]-3-methoxycyclohexane-1-carbaldehyde

: 148933-91-9
C₈₀H₁₂₃NO₁₃Si₂

Guidance literature:: Multi-step reaction with 11 steps

1: 95 percent / LiCl, (i-Pr)2NEt / acetonitrile / 1.) 25 deg C, 15 min, 2.) 25 deg C, 6 h

2: Et₃SiH / Rh(PPh₃)3Cl / 2 h / 50 °C

3: 49percent aq. HF / acetonitrile / 3 h / 25 °C

4: imidazole / dimethylformamide / 16 h / 25 °C

6: 98 percent / aq. LiBH₄ / diethyl ether; tetrahydrofuran / 1 h / 25 °C

7: 91 percent / Et₃N, DMAP / CH₂Cl₂ / 24 h / 25 °C

8: 91 percent / LiEt₃BH / tetrahydrofuran / 2.5 h / 25 °C

9: 85 percent / 4-pyrrolidinopyridine, (i-Pr)2NEt, 1,3-diisopropylcarbodiimide / CH₂Cl₂ / 24 h / -20 °C

10: aq. 4-methylmorpholine-N-oxide, OsO₄ / acetone / 16 h / 25 °C

11: Pb(OAc)4, Na₂CO₃ / benzene / 1.5 h / 25 °C

With 1H-imidazole; lead(IV) acetate; triethylsilane; dmap; osmium(VIII) oxide; lithium borohydride; hydrogen fluoride; lithium triethylborohydride; sodium carbonate; 4-pyrrolidin-1-ylpyridine; 4-methylmorpholine N-oxide; triethylamine; N-ethyl-N,N-diisopropylamine; lithium chloride; diisopropyl-carbodiimide; Wilkinson's catalyst; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetone; acetonitrile; benzene;