1,4-Naphthoquinone,4a,5,8,8a-tetrahydro-8-methoxy-2,4a-dimethyl-(5CI)

Base Information

Chemical Name:1,4-Naphthoquinone,4a,5,8,8a-tetrahydro-8-methoxy-2,4a-dimethyl-(5CI)
CAS No.:824427-16-9
Molecular Formula:C₁₃H₁₆O₃
Molecular Weight:220.268
Hs Code.:
Mol file:824427-16-9.mol

Synonyms:1,4-Naphthoquinone,4a,5,8,8a-tetrahydro-8-methoxy-2,4a-dimethyl- (5CI)

Suppliers and Price of 1,4-Naphthoquinone,4a,5,8,8a-tetrahydro-8-methoxy-2,4a-dimethyl-(5CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,4-Naphthoquinone,4a,5,8,8a-tetrahydro-8-methoxy-2,4a-dimethyl-(5CI)

Chemical Property:

PSA：43.37000
LogP:1.68190

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of 1,4-Naphthoquinone,4a,5,8,8a-tetrahydro-8-methoxy-2,4a-dimethyl-(5CI)

There total 2 articles about 1,4-Naphthoquinone,4a,5,8,8a-tetrahydro-8-methoxy-2,4a-dimethyl-(5CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3036-66-6
1-methoxybuta-1,3-diene

: 137-18-8
2,5-Dimethyl-1,4-benzoquinone

: 824427-16-9
8-methoxy-2,4a-dimethyl-4a,5,8,8a-tetrahydronaphthalene-1,4-dione

: 824427-15-8
(±)-(4aS*,5R*,8aS*)-5-methoxy-2,4a-dimethyl-4a,5,8,8a-tetrahydronaphthalene-1,4-dione

Guidance literature:: With 1,10-Phenanthroline; zinc trifluoromethanesulfonate; In dichloromethane; at 40 ℃; for 24h; Overall yield = 82.5 mg;
DOI:10.1002/asia.201900995

Reference yield:

: 3036-66-6
1-methoxybuta-1,3-diene

: 137-18-8
2,5-Dimethyl-1,4-benzoquinone

: 824427-16-9
8-methoxy-2,4a-dimethyl-4a,5,8,8a-tetrahydronaphthalene-1,4-dione

: 824427-15-8
(4aS*,5R*,8aS*)-5-methoxy-2,4a-dimethyl-4a,5,8,8a-tetrahydronaphthalene-1,4-dione

Guidance literature:: 2,5-Dimethyl-1,4-benzoquinone; With water; zinc trifluoromethanesulfonate; In 1,4-dioxane; at 40 ℃; for 0.166667h; Schlenk technique; Inert atmosphere;

With (3aS,11aS,14aR,16bR)-2,2,13,13-tetra-isopropyl-3a,11a,14a,16b-tetrahydro-bis(1,3-dioxolano[4',5':3,4]pyrrolo)[1,2-a:1',2'-a]naphtho[1,2-d:8,7-d']diimidazole; In 1,4-dioxane; at 40 ℃; for 0.0833333h; Schlenk technique; Inert atmosphere;

1-methoxybuta-1,3-diene; In 1,4-dioxane; at 40 ℃; for 72h; Overall yield = 55.1 percent; Overall yield = 48.5 mg; Schlenk technique; Inert atmosphere;
DOI:10.1002/asia.201900995