6-((1,1-dimethyethyl)diphenylsilyloxy)hexanoic acid 13-tetradecynyl ester

Base Information

Chemical Name:6-((1,1-dimethyethyl)diphenylsilyloxy)hexanoic acid 13-tetradecynyl ester
CAS No.:355011-76-6
Molecular Formula:C₃₆H₅₄O₃Si
Molecular Weight:562.908
Hs Code.:

Synonyms:6-((1,1-dimethyethyl)diphenylsilyloxy)hexanoic acid 13-tetradecynyl ester

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Chemical Property of 6-((1,1-dimethyethyl)diphenylsilyloxy)hexanoic acid 13-tetradecynyl ester

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Technology Process of 6-((1,1-dimethyethyl)diphenylsilyloxy)hexanoic acid 13-tetradecynyl ester

There total 6 articles about 6-((1,1-dimethyethyl)diphenylsilyloxy)hexanoic acid 13-tetradecynyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 18202-12-5
14-hydroxy-1-tetradecyne

: 122846-05-3
6-((1,1-dimethylethyl)diphenylsilyloxy)hexanoic acid

: 355011-76-6
6-((1,1-dimethyethyl)diphenylsilyloxy)hexanoic acid 13-tetradecynyl ester

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In diethyl ether; at 20 ℃;
DOI:10.1021/jo000463n

Reference yield:

: 5675-51-4
1,12-dodecandiol

: 355011-76-6
6-((1,1-dimethyethyl)diphenylsilyloxy)hexanoic acid 13-tetradecynyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 54 percent / conc. HBr

2.1: 3,4-dihydro-2H-pyran / 4-toluenesulfonic acid monohydrate / diethyl ether / 20 °C

2.2: dimethylsulfoxide / 5 - 20 °C

2.3: 4.5 g / 4-toluenesulfonic acid monohydrate / methanol / 20 °C

3.1: 70 percent / DMAP; DCC / diethyl ether / 20 °C

With 3,4-dihydro-2H-pyran; dmap; hydrogen bromide; dicyclohexyl-carbodiimide; p-toluenesulfonic acid monohydrate; In diethyl ether;
DOI:10.1021/jo000463n

Reference yield:

: 3344-77-2
12-bromododecanol

: 355011-76-6
6-((1,1-dimethyethyl)diphenylsilyloxy)hexanoic acid 13-tetradecynyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: 3,4-dihydro-2H-pyran / 4-toluenesulfonic acid monohydrate / diethyl ether / 20 °C

1.2: dimethylsulfoxide / 5 - 20 °C

1.3: 4.5 g / 4-toluenesulfonic acid monohydrate / methanol / 20 °C

2.1: 70 percent / DMAP; DCC / diethyl ether / 20 °C

With 3,4-dihydro-2H-pyran; dmap; dicyclohexyl-carbodiimide; p-toluenesulfonic acid monohydrate; In diethyl ether;
DOI:10.1021/jo000463n