bis(benzylamine)diacetylplatinum(II)

Base Information

• Chemical Name: bis(benzylamine)diacetylplatinum(II)
• CAS No.: 1146625-97-9
• Molecular Formula: C₁₈H₂₄N₂O₂Pt
• Molecular Weight: 495.481
• Mol file: 1146625-97-9.mol

Synonyms:bis(benzylamine)diacetylplatinum(II)

Chemical Property of bis(benzylamine)diacetylplatinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of bis(benzylamine)diacetylplatinum(II)

There total 5 articles about bis(benzylamine)diacetylplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

diacetyl(2,2'-bipyridine)platinum(II) (221700-34-1) + benzylamine (100-46-9) → bis(benzylamine)diacetylplatinum(II) (1146625-97-9)

Guidance literature:

In neat (no solvent); Ar, Schlenk technique; amine added to Pt-complex, stirred for 1 h; solid filtered off, washed (cold diethyl ether at -10 °C), dried (vac.); elem. anal.;

DOI:10.1016/j.jorganchem.2012.05.043

Reference yield: 89.0%

[Pt(COMe)2] + benzylamine (100-46-9) → bis(benzylamine)diacetylplatinum(II) (1146625-97-9)

Guidance literature:

In dichloromethane; (Ar); std. Schlenk technique; ligand was added with stirring to suspn. of Pt complex in CH2Cl2 at -70°C; warmed to room temp.; stirred for 30 min; concd. (vac.); filtered; washed (pentane); dried (vac.); elem. anal.;

DOI:10.1021/om9000499

Reference yield: 60.0%

[Pt(COMe)2(2-PyCH=NOMe)] (1497536-43-2) + benzylamine (100-46-9) → bis(benzylamine)diacetylplatinum(II) (1146625-97-9)

Guidance literature:

at 20 ℃; for 1h; Schlenk technique; Inert atmosphere;

DOI:10.1021/om400812w

upstream raw materials:

benzylamine

diacetyl(2,2'-bipyridine)platinum(II)

di(acetyl)(methoxydimethylglyoxime)platinum

[Pt(COMe)2(2-PyCH=NOMe)]

Downstream raw materials:

acetylmethylcarbonyl(benzylamine)platinum

C₁₆H₁₇N₃O₂Pt

C₁₆H₁₆FN₃O₂Pt

C₁₇H₁₈FN₃O₂Pt