10-[4-(2,2-diphenylethenyl)phenyl]-6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole-5-carbaldehyde

Base Information

Chemical Name:10-[4-(2,2-diphenylethenyl)phenyl]-6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole-5-carbaldehyde
CAS No.:1315509-05-7
Molecular Formula:C₃₆H₂₉NO
Molecular Weight:491.632
Hs Code.:

Synonyms:10-[4-(2,2-diphenylethenyl)phenyl]-6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole-5-carbaldehyde

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Chemical Property of 10-[4-(2,2-diphenylethenyl)phenyl]-6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole-5-carbaldehyde

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Technology Process of 10-[4-(2,2-diphenylethenyl)phenyl]-6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole-5-carbaldehyde

There total 5 articles about 10-[4-(2,2-diphenylethenyl)phenyl]-6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole-5-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 1315509-04-6
10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 1315509-05-7
10-[4-(2,2-diphenylethenyl)phenyl]-6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole-5-carbaldehyde

Guidance literature:: N,N-dimethyl-formamide; With trichlorophosphate; at 10 ℃; for 0.5h;

10-[4-(2,2-diphenylethenyl)phenyl]-6b,-7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole; In N,N-dimethyl-formamide; at 20 ℃; for 2h;
DOI:10.1016/j.dyepig.2011.02.009

Reference yield:

: 1315509-03-5
6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole

: 1315509-05-7
10-[4-(2,2-diphenylethenyl)phenyl]-6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole-5-carbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1.1: tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate / 5,5-dimethyl-1,3-cyclohexadiene / 16 h / 120 °C

2.1: trichlorophosphate / 0.5 h / 10 °C

2.2: 2 h / 20 °C

With tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate; trichlorophosphate; In 5,5-dimethyl-1,3-cyclohexadiene;
DOI:10.1016/j.dyepig.2011.02.009

Reference yield:

: 120-92-3
cyclopentanone

: 1315509-05-7
10-[4-(2,2-diphenylethenyl)phenyl]-6b,7,8,9,9a,10-hexahydrobenzo[g]cyclopenta[b]indole-5-carbaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium acetate; acetic acid / dichloromethane; water / 2 h / Reflux

2.1: sodium tetrahydroborate; acetic acid / 24 h / 20 °C

3.1: tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate / 5,5-dimethyl-1,3-cyclohexadiene / 16 h / 120 °C

4.1: trichlorophosphate / 0.5 h / 10 °C

4.2: 2 h / 20 °C

With sodium tetrahydroborate; tri-tert-butyl phosphine; potassium tert-butylate; sodium acetate; palladium diacetate; acetic acid; trichlorophosphate; In 5,5-dimethyl-1,3-cyclohexadiene; dichloromethane; water;
DOI:10.1016/j.dyepig.2011.02.009