[Pt(II)(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine(1-))(CC-C₆H₄-CH=C(CN)₂)]

Base Information

• Chemical Name: [Pt(II)(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine(1-))(CC-C₆H₄-CH=C(CN)₂)]
• CAS No.: 1429662-07-6
• Molecular Formula: C₃₆H₃₂N₄Pt
• Molecular Weight: 715.757
• Mol file: 1429662-07-6.mol

Synonyms:[Pt(II)(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine(1-))(CC-C₆H₄-CH=C(CN)₂)]

Chemical Property of [Pt(II)(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine(1-))(CC-C₆H₄-CH=C(CN)₂)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(II)(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine(1-))(CC-C₆H₄-CH=C(CN)₂)]

There total 3 articles about [Pt(II)(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine(1-))(CC-C₆H₄-CH=C(CN)₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

[Pt(II)(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine(1-))(4-CC-C6H4-CHO)] (1429662-09-8) + malononitrile (109-77-3) → [Pt(II)(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine(1-))(CC-C6H4-CH=C(CN)2)] (1429662-07-6)

Guidance literature:

With aluminum oxide; In toluene; at 60 ℃; for 18h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ic302478e

Reference yield:

(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine)platinum(II) chloride (693782-72-8) → [Pt(II)(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine(1-))(CC-C6H4-CH=C(CN)2)] (1429662-07-6)

Guidance literature:

Multi-step reaction with 2 steps

1: copper(l) iodide; potassium carbonate / dichloromethane; methanol / 20 °C / Inert atmosphere; Schlenk technique

2: aluminum oxide / toluene / 18 h / 60 °C / Inert atmosphere; Schlenk technique

With aluminum oxide; copper(l) iodide; potassium carbonate; In methanol; dichloromethane; toluene; 2: |Knoevenagel Condensation;

DOI:10.1021/ic302478e

Reference yield:

4-[(trimethylsilyl)ethynyl]bezaldehyde (77123-57-0) → [Pt(II)(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine(1-))(CC-C6H4-CH=C(CN)2)] (1429662-07-6)

Guidance literature:

Multi-step reaction with 2 steps

1: copper(l) iodide; potassium carbonate / dichloromethane; methanol / 20 °C / Inert atmosphere; Schlenk technique

2: aluminum oxide / toluene / 18 h / 60 °C / Inert atmosphere; Schlenk technique

With aluminum oxide; copper(l) iodide; potassium carbonate; In methanol; dichloromethane; toluene; 2: |Knoevenagel Condensation;

DOI:10.1021/ic302478e

upstream raw materials:

[Pt(II)(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine(1-))(4-CC-C₆H₄-CHO)]

malononitrile

(4,4′-di(tert-butyl)-6-phenyl-2,2′-bipyridine)platinum(II) chloride

4-[(trimethylsilyl)ethynyl]bezaldehyde