5-benzyloxy-3-carbomethoxy-1,4-dimethoxy-7-methoxymethoxy-2,6-dimethylnaphthalene

Base Information

Chemical Name:5-benzyloxy-3-carbomethoxy-1,4-dimethoxy-7-methoxymethoxy-2,6-dimethylnaphthalene
CAS No.:148117-03-7
Molecular Formula:C₂₅H₂₈O₇
Molecular Weight:440.493
Hs Code.:

Synonyms:5-benzyloxy-3-carbomethoxy-1,4-dimethoxy-7-methoxymethoxy-2,6-dimethylnaphthalene

Suppliers and Price of 5-benzyloxy-3-carbomethoxy-1,4-dimethoxy-7-methoxymethoxy-2,6-dimethylnaphthalene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 5-benzyloxy-3-carbomethoxy-1,4-dimethoxy-7-methoxymethoxy-2,6-dimethylnaphthalene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 5-benzyloxy-3-carbomethoxy-1,4-dimethoxy-7-methoxymethoxy-2,6-dimethylnaphthalene

There total 5 articles about 5-benzyloxy-3-carbomethoxy-1,4-dimethoxy-7-methoxymethoxy-2,6-dimethylnaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 148117-02-6
5-benzyloxy-3-bromo-1,4-dimethoxy-7-methoxymethoxy-2,6-dimethylnaphthalene

: 79-22-1
methyl chloroformate

: 148117-03-7
5-benzyloxy-3-carbomethoxy-1,4-dimethoxy-7-methoxymethoxy-2,6-dimethylnaphthalene

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; for 4h;
DOI:10.1139/cjc-79-11-1711

Reference yield:

: 85954-40-1
3-Bromo-5,7-dihydroxy-2,6-dimethyl-[1,4]naphthoquinone

: 148117-03-7
5-benzyloxy-3-carbomethoxy-1,4-dimethoxy-7-methoxymethoxy-2,6-dimethylnaphthalene

Guidance literature:: Multi-step reaction with 4 steps

1.1: P₂O₅ / CHCl₃

2.1: 90 percent / Ag₂O / CHCl₃ / 24 h / 23 °C

3.1: CeCl₃*7H₂O; NaBH₄ / dioxane; H₂O / 0 °C

3.2: 89 percent / 50 percent NaOH / dioxane; H₂O / 1 h / 23 °C

4.1: 98 percent / n-BuLi / tetrahydrofuran / 4 h / -78 - 20 °C

With sodium tetrahydroborate; n-butyllithium; cerium(III) chloride; phosphorus pentoxide; silver(l) oxide; In tetrahydrofuran; 1,4-dioxane; chloroform; water;
DOI:10.1139/cjc-79-11-1711

Reference yield:

: 85954-41-2
3-Bromo-5-hydroxy-7-methoxymethoxy-2,6-dimethyl-[1,4]naphthoquinone

: 148117-03-7
5-benzyloxy-3-carbomethoxy-1,4-dimethoxy-7-methoxymethoxy-2,6-dimethylnaphthalene

Guidance literature:: Multi-step reaction with 3 steps

1.1: 90 percent / Ag₂O / CHCl₃ / 24 h / 23 °C

2.1: CeCl₃*7H₂O; NaBH₄ / dioxane; H₂O / 0 °C

2.2: 89 percent / 50 percent NaOH / dioxane; H₂O / 1 h / 23 °C

3.1: 98 percent / n-BuLi / tetrahydrofuran / 4 h / -78 - 20 °C

With sodium tetrahydroborate; n-butyllithium; cerium(III) chloride; silver(l) oxide; In tetrahydrofuran; 1,4-dioxane; chloroform; water;
DOI:10.1139/cjc-79-11-1711