(3-Allyloxy-5-{2,2,2-trifluoro-1-[(Z)-hydroxyimino]-ethyl}-phenyl)-carbamic acid tert-butyl ester

Base Information

Chemical Name:(3-Allyloxy-5-{2,2,2-trifluoro-1-[(Z)-hydroxyimino]-ethyl}-phenyl)-carbamic acid tert-butyl ester
CAS No.:212208-04-3
Molecular Formula:C₁₆H₁₉F₃N₂O₄
Molecular Weight:360.333
Hs Code.:

Synonyms:(3-Allyloxy-5-{2,2,2-trifluoro-1-[(Z)-hydroxyimino]-ethyl}-phenyl)-carbamic acid tert-butyl ester

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Chemical Property of (3-Allyloxy-5-{2,2,2-trifluoro-1-[(Z)-hydroxyimino]-ethyl}-phenyl)-carbamic acid tert-butyl ester

Chemical Property:

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Technology Process of (3-Allyloxy-5-{2,2,2-trifluoro-1-[(Z)-hydroxyimino]-ethyl}-phenyl)-carbamic acid tert-butyl ester

There total 11 articles about (3-Allyloxy-5-{2,2,2-trifluoro-1-[(Z)-hydroxyimino]-ethyl}-phenyl)-carbamic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13036-02-7
Dimethyl 5-hydroxyisophthalate

: 212208-04-3
(3-Allyloxy-5-{2,2,2-trifluoro-1-[(Z)-hydroxyimino]-ethyl}-phenyl)-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 11 steps

1: K₂CO₃ / acetone / Heating

2: aq. NaOH / methanol

4: aq. NaBH₄ / tetrahydrofuran

5: Dess-Martin periodinane / CH₂Cl₂

6: TBAF / tetrahydrofuran

7: aq. HCl

8: Dess-Martin periodinane, TFA / CH₂Cl₂

9: NH₂OH*HCl, pyridine / 60 °C

10: aq. NaOH / methanol

11: DPPA, Et₃N / Heating

With pyridine; hydrogenchloride; sodium hydroxide; sodium tetrahydroborate; diphenyl-phosphinic acid; hydroxylamine hydrochloride; tetrabutyl ammonium fluoride; potassium carbonate; Dess-Martin periodane; triethylamine; trifluoroacetic acid; In tetrahydrofuran; methanol; dichloromethane; acetone;
DOI:10.1021/ja9817186

Reference yield:

: 21368-39-8
dimethyl 5-(prop-2-en-1-yloxy)benzene-1,3-dicarboxylate

: 212208-04-3
(3-Allyloxy-5-{2,2,2-trifluoro-1-[(Z)-hydroxyimino]-ethyl}-phenyl)-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 10 steps

1: aq. NaOH / methanol

3: aq. NaBH₄ / tetrahydrofuran

4: Dess-Martin periodinane / CH₂Cl₂

5: TBAF / tetrahydrofuran

6: aq. HCl

7: Dess-Martin periodinane, TFA / CH₂Cl₂

8: NH₂OH*HCl, pyridine / 60 °C

9: aq. NaOH / methanol

10: DPPA, Et₃N / Heating

With pyridine; hydrogenchloride; sodium hydroxide; sodium tetrahydroborate; diphenyl-phosphinic acid; hydroxylamine hydrochloride; tetrabutyl ammonium fluoride; Dess-Martin periodane; triethylamine; trifluoroacetic acid; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ja9817186

Reference yield:

: 900800-44-4
methyl 3-allyloxy-5-(hydroxymethyl)benzoate

: 212208-04-3
(3-Allyloxy-5-{2,2,2-trifluoro-1-[(Z)-hydroxyimino]-ethyl}-phenyl)-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: Dess-Martin periodinane / CH₂Cl₂

2: TBAF / tetrahydrofuran

3: aq. HCl

4: Dess-Martin periodinane, TFA / CH₂Cl₂

5: NH₂OH*HCl, pyridine / 60 °C

6: aq. NaOH / methanol

7: DPPA, Et₃N / Heating

With pyridine; hydrogenchloride; sodium hydroxide; diphenyl-phosphinic acid; hydroxylamine hydrochloride; tetrabutyl ammonium fluoride; Dess-Martin periodane; triethylamine; trifluoroacetic acid; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ja9817186