{chloro-[dichloro-(9-methyl-9H-fluoren-9-yl)-silanyl]-methylene}-(2,4,6-tri-tert-butyl-phenyl)-phosphane

Base Information

Chemical Name:{chloro-[dichloro-(9-methyl-9H-fluoren-9-yl)-silanyl]-methylene}-(2,4,6-tri-tert-butyl-phenyl)-phosphane
CAS No.:875089-80-8
Molecular Formula:C₃₃H₄₀Cl₃PSi
Molecular Weight:602.099
Hs Code.:

{chloro-[dichloro-(9-methyl-9<i>H</i>-fluoren-9-yl)-silanyl]-methylene}-(2,4,6-tri-<i>tert</i>-butyl-phenyl)-phosphane

Synonyms:{chloro-[dichloro-(9-methyl-9H-fluoren-9-yl)-silanyl]-methylene}-(2,4,6-tri-tert-butyl-phenyl)-phosphane

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Chemical Property of {chloro-[dichloro-(9-methyl-9H-fluoren-9-yl)-silanyl]-methylene}-(2,4,6-tri-tert-butyl-phenyl)-phosphane

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Technology Process of {chloro-[dichloro-(9-methyl-9H-fluoren-9-yl)-silanyl]-methylene}-(2,4,6-tri-tert-butyl-phenyl)-phosphane

There total 1 articles about {chloro-[dichloro-(9-methyl-9H-fluoren-9-yl)-silanyl]-methylene}-(2,4,6-tri-tert-butyl-phenyl)-phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 100281-24-1
2,2-dichloro-1-(2,4,6-tri-tert-butylphenyl)-1-phosphaethene

: 221315-63-5
trichloro(9-methylfluoren-9-yl)silane

: 875089-80-8
{chloro-[dichloro-(9-methyl-9H-fluoren-9-yl)-silanyl]-methylene}-(2,4,6-tri-tert-butyl-phenyl)-phosphane

Guidance literature:: 2,2-dichloro-1-(2,4,6-tri-tert-butylphenyl)-1-phosphaethene; With n-butyllithium; In tetrahydrofuran; hexane; at -80 ℃;

trichloro(9-methylfluoren-9-yl)silane; In tetrahydrofuran; hexane; at -80 - 20 ℃; for 2h;
DOI:10.1002/ejic.200400595

Reference yield: 100.0%

: 875089-80-8
{chloro-[dichloro-(9-methyl-9H-fluoren-9-yl)-silanyl]-methylene}-(2,4,6-tri-tert-butyl-phenyl)-phosphane

: 875089-78-4
C₃₃H₄₀Cl₂LiPSi

Guidance literature:: With tert.-butyl lithium; In diethyl ether; hexane; at -80 - 20 ℃; for 2h;
DOI:10.1002/ejic.200400595

Reference yield:

: 875089-80-8
{chloro-[dichloro-(9-methyl-9H-fluoren-9-yl)-silanyl]-methylene}-(2,4,6-tri-tert-butyl-phenyl)-phosphane

: {[dimethoxy-(9-methyl-9H-fluoren-9-yl)-silanyl]-methylene}-(2,4,6-tri-tert-butyl-phenyl)-phosphane

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / t-BuLi / diethyl ether; hexane / 2 h / -80 - 20 °C

2: 88 percent / diethyl ether

With tert.-butyl lithium; In diethyl ether; hexane;
DOI:10.1002/ejic.200400595