6-hydroxyallylisopseudocumenol

Base Information

• Chemical Name: 6-hydroxyallylisopseudocumenol
• CAS No.: 186743-38-4
• Molecular Formula: C₁₂H₁₆O₂
• Molecular Weight: 192.258
• Mol file: 186743-38-4.mol

Synonyms:6-hydroxyallylisopseudocumenol

Chemical Property of 6-hydroxyallylisopseudocumenol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 6-hydroxyallylisopseudocumenol

There total 4 articles about 6-hydroxyallylisopseudocumenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

6-hydroxyethylallylisopseudocumenol (186743-37-3) → 6-hydroxyallylisopseudocumenol (186743-38-4)

Guidance literature:

With dihydrogen peroxide; toluene-4-sulfonic acid; In tetrahydrofuran; water; at 20 ℃; for 72h;

DOI:10.1021/tx960087v

Reference yield:

6-acetylallylisopseudocumenol (186743-36-2) → 6-hydroxyallylisopseudocumenol (186743-38-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 94 percent / LiAlH₄ / diethyl ether / 0.5 h / 0 - 20 °C

2: 76 percent / H₂O₂; p-toluenesulfonic acid / tetrahydrofuran; H₂O / 72 h / 20 °C

With dihydrogen peroxide; toluene-4-sulfonic acid; lithium aluminium tetrahydride; In tetrahydrofuran; diethyl ether; water;

DOI:10.1021/tx960087v

Reference yield:

2,3,5-trimethyl-1-acetoxybenzene (34649-27-9) → 6-hydroxyallylisopseudocumenol (186743-38-4)

Guidance literature:

Multi-step reaction with 4 steps

1: 85 percent / AlCl₃ / 1.5 h / 100 °C / Heating

2: 96 percent / K₂CO₃ / acetone / 48 h / Heating

3: 94 percent / LiAlH₄ / diethyl ether / 0.5 h / 0 - 20 °C

4: 76 percent / H₂O₂; p-toluenesulfonic acid / tetrahydrofuran; H₂O / 72 h / 20 °C

With dihydrogen peroxide; potassium carbonate; toluene-4-sulfonic acid; lithium aluminium tetrahydride; aluminium trichloride; In tetrahydrofuran; diethyl ether; water; acetone;

DOI:10.1021/tx960087v

upstream raw materials:

6-hydroxyethylallylisopseudocumenol

2,3,5-trimethyl-1-acetoxybenzene

6-acetylisopseudocumenol

6-acetylallylisopseudocumenol

Downstream raw materials:

6-methoxyallylisopseudocumenol