Carbonic acid, 2-propenyl 2,6,6-trimethyl-1-cyclohexen-1-yl ester (9CI)

Base Information

Chemical Name:Carbonic acid, 2-propenyl 2,6,6-trimethyl-1-cyclohexen-1-yl ester (9CI)
CAS No.:812639-01-3
Molecular Formula:C13H20 O3
Molecular Weight:224.3
Hs Code.:
Mol file:812639-01-3.mol

Synonyms:Carbonicacid, 2-propenyl 2,6,6-trimethyl-1-cyclohexen-1-yl ester (9CI)

Suppliers and Price of Carbonic acid, 2-propenyl 2,6,6-trimethyl-1-cyclohexen-1-yl ester (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Carbonic acid, 2-propenyl 2,6,6-trimethyl-1-cyclohexen-1-yl ester (9CI)

Chemical Property:

PSA：35.53000
LogP:4.15730

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Carbonic acid, 2-propenyl 2,6,6-trimethyl-1-cyclohexen-1-yl ester (9CI)

There total 4 articles about Carbonic acid, 2-propenyl 2,6,6-trimethyl-1-cyclohexen-1-yl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 2408-37-9
2,2,6-trimethylcyclohexan-1-one

: 2937-50-0
Allyl chloroformate

: 812639-01-3
allyl 2,6,6-trimethylcyclohex-1-enyl carbonate

Guidance literature:: 2,2,6-trimethylcyclohexan-1-one; With lithium hexamethyldisilazane; In tetrahydrofuran; at 0 ℃; for 1h;

Allyl chloroformate; In tetrahydrofuran; at -78 ℃;
DOI:10.1021/ja061853f

Reference yield: 48.0%

: 63934-48-5
allyl cyanoformate

: 2408-37-9
2,2,6-trimethylcyclohexan-1-one

: 873436-31-8
allyl 1,3,3-trimethyl-2-oxocyclohexanecarboxylate

: 812639-01-3
allyl 2,6,6-trimethylcyclohex-1-enyl carbonate

Guidance literature:: 2,2,6-trimethylcyclohexan-1-one; With lithium diisopropyl amide; In tetrahydrofuran; at -78 - 0 ℃; for 1h;

allyl cyanoformate; With N,N,N,N,N,N-hexamethylphosphoric triamide; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1002/anie.200502018

Reference yield:

: C₁₀H₁₉N₃O

: 812639-01-3
allyl 2,6,6-trimethylcyclohex-1-enyl carbonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 82 percent / aq. HCl / diethyl ether; H₂O / 3 h / 23 °C

2.1: LiHMDS / tetrahydrofuran / 1 h / 0 °C

2.2: 86 percent / tetrahydrofuran / -78 °C

With hydrogenchloride; lithium hexamethyldisilazane; In tetrahydrofuran; diethyl ether; water;
DOI:10.1021/ja061853f