2-bromo-3-[3-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1,1-dimethyl-propyl hydroperoxide

Base Information

Chemical Name:2-bromo-3-[3-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1,1-dimethyl-propyl hydroperoxide
CAS No.:295311-78-3
Molecular Formula:C₁₇H₂₉BrO₃Si
Molecular Weight:389.405
Hs Code.:

2-bromo-3-[3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-phenyl]-1,1-dimethyl-propyl hydroperoxide

Synonyms:2-bromo-3-[3-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1,1-dimethyl-propyl hydroperoxide

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Chemical Property of 2-bromo-3-[3-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1,1-dimethyl-propyl hydroperoxide

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Technology Process of 2-bromo-3-[3-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1,1-dimethyl-propyl hydroperoxide

There total 3 articles about 2-bromo-3-[3-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1,1-dimethyl-propyl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 295311-74-9
tert-butyl-dimethyl-[3-(3-methyl-but-2-enyl)-phenoxy]-silane

: 295311-78-3
2-bromo-3-[3-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1,1-dimethyl-propyl hydroperoxide

Guidance literature:: With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; dihydrogen peroxide; In diethyl ether; at -40 - 0 ℃; for 1.5h;
DOI:10.1016/S0040-4020(00)00457-9

Reference yield:

: 65423-56-5
1-bromo-3-[(tert-butyldimethylsilyl)oxy]benzene

: 295311-78-3
2-bromo-3-[3-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1,1-dimethyl-propyl hydroperoxide

Guidance literature:: Multi-step reaction with 2 steps

1.1: Mg; bromoethane / tetrahydrofuran / 2 h / Heating

1.2: 38 percent / tetrahydrofuran / 3 h / Heating

2.1: 80 percent / H₂O₂; 1,3-dibromo-5,5-dimethylhydantoin / diethyl ether / 1.5 h / -40 - 0 °C

With ethyl bromide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; dihydrogen peroxide; magnesium; In tetrahydrofuran; diethyl ether; 1.1: Metallation / 1.2: Grignard reaction / 2.1: Oxidation;
DOI:10.1016/S0040-4020(00)00457-9

Reference yield:

: 870-63-3
prenyl bromide

: 295311-78-3
2-bromo-3-[3-(tert-butyl-dimethyl-silanyloxy)-phenyl]-1,1-dimethyl-propyl hydroperoxide

Guidance literature:: Multi-step reaction with 2 steps

1.1: Mg; bromoethane / tetrahydrofuran / 2 h / Heating

1.2: 38 percent / tetrahydrofuran / 3 h / Heating

2.1: 80 percent / H₂O₂; 1,3-dibromo-5,5-dimethylhydantoin / diethyl ether / 1.5 h / -40 - 0 °C

With ethyl bromide; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; dihydrogen peroxide; magnesium; In tetrahydrofuran; diethyl ether; 1.1: Metallation / 1.2: Grignard reaction / 2.1: Oxidation;
DOI:10.1016/S0040-4020(00)00457-9