(4R,5S,6S)-4-[(1S,2R,3R)-7-Benzenesulfonyl-1-((2S,4S,5R,6R)-4-methoxy-6-methyl-5-triethylsilanyloxy-tetrahydro-pyran-2-yloxy)-3-methyl-2,3-bis-triethylsilanyloxy-heptyl]-2,2-di-tert-butyl-6-isopropenyl-5-methyl-[1,3,2]dioxasilinane

Base Information

• Chemical Name: (4R,5S,6S)-4-[(1S,2R,3R)-7-Benzenesulfonyl-1-((2S,4S,5R,6R)-4-methoxy-6-methyl-5-triethylsilanyloxy-tetrahydro-pyran-2-yloxy)-3-methyl-2,3-bis-triethylsilanyloxy-heptyl]-2,2-di-tert-butyl-6-isopropenyl-5-methyl-[1,3,2]dioxasilinane
• CAS No.: 129986-52-3
• Molecular Formula: C₅₄H₁₀₄O₁₀SSi₄
• Molecular Weight: 1057.82
• Mol file: 129986-52-3.mol

Synonyms:(4R,5S,6S)-4-[(1S,2R,3R)-7-Benzenesulfonyl-1-((2S,4S,5R,6R)-4-methoxy-6-methyl-5-triethylsilanyloxy-tetrahydro-pyran-2-yloxy)-3-methyl-2,3-bis-triethylsilanyloxy-heptyl]-2,2-di-tert-butyl-6-isopropenyl-5-methyl-[1,3,2]dioxasilinane

Chemical Property of (4R,5S,6S)-4-[(1S,2R,3R)-7-Benzenesulfonyl-1-((2S,4S,5R,6R)-4-methoxy-6-methyl-5-triethylsilanyloxy-tetrahydro-pyran-2-yloxy)-3-methyl-2,3-bis-triethylsilanyloxy-heptyl]-2,2-di-tert-butyl-6-isopropenyl-5-methyl-[1,3,2]dioxasilinane

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of (4R,5S,6S)-4-[(1S,2R,3R)-7-Benzenesulfonyl-1-((2S,4S,5R,6R)-4-methoxy-6-methyl-5-triethylsilanyloxy-tetrahydro-pyran-2-yloxy)-3-methyl-2,3-bis-triethylsilanyloxy-heptyl]-2,2-di-tert-butyl-6-isopropenyl-5-methyl-[1,3,2]dioxasilinane

There total 1 articles about (4R,5S,6S)-4-[(1S,2R,3R)-7-Benzenesulfonyl-1-((2S,4S,5R,6R)-4-methoxy-6-methyl-5-triethylsilanyloxy-tetrahydro-pyran-2-yloxy)-3-methyl-2,3-bis-triethylsilanyloxy-heptyl]-2,2-di-tert-butyl-6-isopropenyl-5-methyl-[1,3,2]dioxasilinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

<4R-<4α(1R*,2R*,3R*),5α,6α>>-<1-<2,2-bis(1,1-dimethylethyl)-5-methyl-6-(1-methylethenyl)-1,3-dioxa-2-silacycyclohex-4-yl>-2,3-bis<(triethylsilyl)oxy>-3-methyl-7-(phenylthio)heptyl> 2,6-dideoxy-3-O-methyl-4-O-(triethylsilyl)-β-D-ribo-hexopyr... (125846-31-3,130061-23-3) → (4R,5S,6S)-4-[(1S,2R,3R)-7-Benzenesulfonyl-1-((2S,4S,5R,6R)-4-methoxy-6-methyl-5-triethylsilanyloxy-tetrahydro-pyran-2-yloxy)-3-methyl-2,3-bis-triethylsilanyloxy-heptyl]-2,2-di-tert-butyl-6-isopropenyl-5-methyl-[1,3,2]dioxasilinane (129986-52-3)

Guidance literature:

With 4-methyl-morpholine; osmium(VIII) oxide; In water; acetone; for 0.333333h; Ambient temperature;

DOI:10.1016/S0040-4039(00)93423-3

upstream raw materials:

<4R-<4α(1R^*,2R^*,3R^*),5α,6α>>-<1-<2,2-bis(1,1-dimethylethyl)-5-methyl-6-(1-methylethenyl)-1,3-dioxa-2-silacycyclohex-4-yl>-2,3-bis<(triethylsilyl)oxy>-3-methyl-7-(phenylthio)heptyl> 2,6-dideoxy-3-O-methyl-4-O-(triethylsilyl)-β-D-ribo-hexopyr...