Technology Process of C35H47N3O9Si
There total 10 articles about C35H47N3O9Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate;
In
dimethyl sulfoxide;
at 16 - 20 ℃;
DOI:10.1002/chem.200700033
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 86 percent / diisobutylaluminium hydride / CH2Cl2 / 1.5 h / -78 °C
2: 100 percent / potassium hexamethyldisilazide / diethyl ether / -78 - 20 °C
3: 69 percent / triethylamine; aq. NaOCl / CH2Cl2 / 0 - 20 °C
4: 77 percent / acetic acid; hydrogen / Pd(OH)2/C / methanol / 0.25 h / 20 °C
5: 65 percent / 2-(1H-benzotriazole-1-yl)-1,1,3,3-tetramethyluronium*BF4 / dimethylsulfoxide / 16 - 20 °C
With
sodium hypochlorite; hydrogen; potassium hexamethylsilazane; diisobutylaluminium hydride; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; acetic acid; triethylamine;
palladium dihydroxide;
In
methanol; diethyl ether; dichloromethane; dimethyl sulfoxide;
2: Wittig methylenation;
DOI:10.1002/chem.200700033
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 100 percent / potassium hexamethyldisilazide / diethyl ether / -78 - 20 °C
2: 69 percent / triethylamine; aq. NaOCl / CH2Cl2 / 0 - 20 °C
3: 77 percent / acetic acid; hydrogen / Pd(OH)2/C / methanol / 0.25 h / 20 °C
4: 65 percent / 2-(1H-benzotriazole-1-yl)-1,1,3,3-tetramethyluronium*BF4 / dimethylsulfoxide / 16 - 20 °C
With
sodium hypochlorite; hydrogen; potassium hexamethylsilazane; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; acetic acid; triethylamine;
palladium dihydroxide;
In
methanol; diethyl ether; dichloromethane; dimethyl sulfoxide;
1: Wittig methylenation;
DOI:10.1002/chem.200700033