Dimethyl αH-(tridecachlorotriphenyl)methane-4,4'-dicarboxylate

Base Information

• Chemical Name: Dimethyl αH-(tridecachlorotriphenyl)methane-4,4'-dicarboxylate
• CAS No.: 155202-97-4
• Molecular Formula: C₂₃H₇Cl₁₃O₄
• Molecular Weight: 808.195
• Mol file: 155202-97-4.mol

Synonyms:Dimethyl αH-(tridecachlorotriphenyl)methane-4,4'-dicarboxylate

Chemical Property of Dimethyl αH-(tridecachlorotriphenyl)methane-4,4'-dicarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Dimethyl αH-(tridecachlorotriphenyl)methane-4,4'-dicarboxylate

There total 1 articles about Dimethyl αH-(tridecachlorotriphenyl)methane-4,4'-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diazomethane (186581-53-3,908094-01-9,334-88-3) + (4,4'-Bis(trichloromethyl)triphenyl)methane (155202-94-1) → Methyl αH-(tetradecachlorotriphenyl)methane-4-carboxylate (79839-43-3) + Dimethyl αH-(tridecachlorotriphenyl)methane-4,4'-dicarboxylate (155202-97-4)

Guidance literature:

Yield given. Multistep reaction. Yields of byproduct given;

DOI:10.1021/jo00088a052

Reference yield: 71.0%

Dimethyl αH-(tridecachlorotriphenyl)methane-4,4'-dicarboxylate (155202-97-4) → αH-(Tridecachlorotriphenyl)methane-4,4'-dicarboxylic acid (155202-96-3)

Guidance literature:

With sulfuric acid; at 115 ℃; for 4h;

DOI:10.1021/jo00088a052

Reference yield:

Dimethyl αH-(tridecachlorotriphenyl)methane-4,4'-dicarboxylate (155202-97-4) → (Tridecachloro-4,4'-bis(methoxycarbonyl)triphenyl)methyl radical

Guidance literature:

With tetra(n-butyl)ammonium hydroxide; iodine; Yield given. Multistep reaction; 1.) THF, r.t., 6 h, 2.) r.t., 1 h;

DOI:10.1021/jo00088a052

upstream raw materials:

diazomethane

(4,4'-Bis(trichloromethyl)triphenyl)methane

Downstream raw materials:

αH-(Tridecachlorotriphenyl)methane-4,4'-dicarboxylic acid