1'-O-trifluoromethanesulfonyl-2,3,4,6,3',4',6'-,hepta-O-benzoylsucrose

Base Information

• Chemical Name: 1'-O-trifluoromethanesulfonyl-2,3,4,6,3',4',6'-,hepta-O-benzoylsucrose
• CAS No.: 1434596-35-6
• Molecular Formula: C₆₂H₄₉F₃O₂₀S
• Molecular Weight: 1203.12
• Mol file: 1434596-35-6.mol

Synonyms:1'-O-trifluoromethanesulfonyl-2,3,4,6,3',4',6'-,hepta-O-benzoylsucrose

Chemical Property of 1'-O-trifluoromethanesulfonyl-2,3,4,6,3',4',6'-,hepta-O-benzoylsucrose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1'-O-trifluoromethanesulfonyl-2,3,4,6,3',4',6'-,hepta-O-benzoylsucrose

There total 1 articles about 1'-O-trifluoromethanesulfonyl-2,3,4,6,3',4',6'-,hepta-O-benzoylsucrose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

trifluoromethylsulfonic anhydride (358-23-6) + 3,4,6-tri-O-benzoyl-β-D-fructofuranosyl-2,3,4,6-tetra-O-benzoyl-α-D-glucopyranoside (309261-83-4) → 1'-O-trifluoromethanesulfonyl-2,3,4,6,3',4',6'-,hepta-O-benzoylsucrose (1434596-35-6)

Guidance literature:

With 2,6-dimethylpyridine; In dichloromethane; at -78 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ol401044h

Reference yield: 60.0%

1'-O-trifluoromethanesulfonyl-2,3,4,6,3',4',6'-,hepta-O-benzoylsucrose (1434596-35-6) → 1'-deoxy-1'-fluoro-2,3,4,6,3',4',6'-hepta-O-benzoylsucrose (1434596-38-9)

Guidance literature:

With potassium fluoride; [2.2.2]cryptande; In acetonitrile; at 135 ℃; for 0.166667h; Reagent/catalyst; Time; Sealed tube; Inert atmosphere;

DOI:10.1021/ol401044h

Reference yield: 59.0%

1'-O-trifluoromethanesulfonyl-2,3,4,6,3',4',6'-,hepta-O-benzoylsucrose (1434596-35-6) → 1'-azido-2,3,4,6,3',4',6'-hepta-O-benzoylsucrose

Guidance literature:

With sodium azide; In N,N-dimethyl-formamide; at 20 ℃;

DOI:10.1002/anie.202016802

upstream raw materials:

trifluoromethylsulfonic anhydride

3,4,6-tri-O-benzoyl-β-D-fructofuranosyl-2,3,4,6-tetra-O-benzoyl-α-D-glucopyranoside

Downstream raw materials:

1'-deoxy-1'-fluoro-2,3,4,6,3',4',6'-hepta-O-benzoylsucrose

2,3,4,6,1,3,4,6-octa-O-benzoylsucrose