Aldehydo-3,5-didesoxy-6-O-(p-tosyl)-2,4-O-isopropyliden-D-erythro-hexose-trimethylendithioacetal

Base Information

Chemical Name:Aldehydo-3,5-didesoxy-6-O-(p-tosyl)-2,4-O-isopropyliden-D-erythro-hexose-trimethylendithioacetal
CAS No.:82087-41-0
Molecular Formula:C₁₉H₂₈O₅S₃
Molecular Weight:432.626
Hs Code.:

Synonyms:Aldehydo-3,5-didesoxy-6-O-(p-tosyl)-2,4-O-isopropyliden-D-erythro-hexose-trimethylendithioacetal

Suppliers and Price of Aldehydo-3,5-didesoxy-6-O-(p-tosyl)-2,4-O-isopropyliden-D-erythro-hexose-trimethylendithioacetal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Aldehydo-3,5-didesoxy-6-O-(p-tosyl)-2,4-O-isopropyliden-D-erythro-hexose-trimethylendithioacetal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Aldehydo-3,5-didesoxy-6-O-(p-tosyl)-2,4-O-isopropyliden-D-erythro-hexose-trimethylendithioacetal

There total 1 articles about Aldehydo-3,5-didesoxy-6-O-(p-tosyl)-2,4-O-isopropyliden-D-erythro-hexose-trimethylendithioacetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 65923-96-8
4,5-Dimethyl-1,2,3-thiadiazol

: 98-59-9
p-toluenesulfonyl chloride

: 82087-41-0
Aldehydo-3,5-didesoxy-6-O-(p-tosyl)-2,4-O-isopropyliden-D-erythro-hexose-trimethylendithioacetal

Guidance literature:: With pyridine;

Reference yield:

: 82087-41-0
Aldehydo-3,5-didesoxy-6-O-(p-tosyl)-2,4-O-isopropyliden-D-erythro-hexose-trimethylendithioacetal

: 38401-84-2,69744-43-0,69744-44-1,70427-57-5,70427-58-6,73208-56-7,73208-57-8,75443-93-5,75443-94-6
(2R)-2-Aethyl-1,6-dioxaspiro<4.4>-nonan

Guidance literature:: Multi-step reaction with 7 steps

1: 95 percent / LiAlH₄ / tetrahydrofuran / Heating

2: n-C₄H₉Li / tetrahydrofuran / 1.) -78 degC; 2.) heating to 0 degC

3: 70 percent / LiAlH₄ / tetrahydrofuran / 5 h / Heating

4: 0.14 g / p-toluenesulfonic acid hydrate / dioxane / 0.5 h / 0 °C

5: 1.) n-C₄H₉Li / 1.) THF, hexane, 2h, -20 degC; 2.) -70 degC to room temp.

6: collidine hydrochloride, HgO / 2.5 h / Heating

7: 2N HCl / pentane

With hydrogenchloride; lithium aluminium tetrahydride; n-butyllithium; collidine hydrochloride; toluene-4-sulfonic acid; mercury(II) oxide; In tetrahydrofuran; 1,4-dioxane; pentane;

Reference yield:

: 82087-41-0
Aldehydo-3,5-didesoxy-6-O-(p-tosyl)-2,4-O-isopropyliden-D-erythro-hexose-trimethylendithioacetal

: 38401-84-2,69744-43-0,69744-44-1,70427-57-5,70427-58-6,73208-56-7,73208-57-8,75443-93-5,75443-94-6
(2S,5R,S)-Chalcogran

Guidance literature:: Multi-step reaction with 9 steps

1: 95 percent / LiAlH₄ / tetrahydrofuran / Heating

2: n-C₄H₉Li / tetrahydrofuran / 1.) -78 degC; 2.) heating to 0 degC

3: 70 percent / LiAlH₄ / tetrahydrofuran / 5 h / Heating

4: 93 percent / (C₆H₅)3P, H₅C₂OOC-N=N-COOC₂H₅ / tetrahydrofuran / 12 h

5: 100 mg / NaH / methanol

6: p-toluenesulfonic acid hydrate / dioxane / 0.5 h / 0 °C

7: 1.) n-C₄H₉Li / 1.) THF, hexane, 2h, -20 degC; 2.) -70 degC to room temp.

8: collidine-hydrochloride, HgO / 2.5 h / Heating

9: 2N HCl / pentane

With hydrogenchloride; lithium aluminium tetrahydride; n-butyllithium; 2,4,6-collidine hydrochloride; sodium hydride; toluene-4-sulfonic acid; triphenylphosphine; mercury(II) oxide; diethylazodicarboxylate; In tetrahydrofuran; 1,4-dioxane; methanol; pentane;