benzyl 2,3-O-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside

Base Information

• Chemical Name: benzyl 2,3-O-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside
• CAS No.: 154774-23-9
• Molecular Formula: C₆₉H₆₂O₁₄
• Molecular Weight: 1115.24
• Mol file: 154774-23-9.mol

Synonyms:benzyl 2,3-O-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside

Chemical Property of benzyl 2,3-O-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl 2,3-O-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside

There total 4 articles about benzyl 2,3-O-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

benzyl 4,6-O-benzylidene-2,3-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside → benzyl 2,3-O-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside (154774-23-9)

Guidance literature:

With iodine; In methanol; dichloromethane; for 40h; Heating;

DOI:10.1021/ja00084a015

Reference yield: 99.0%

benzyl 4,6-O-benzylidene-2,3-O-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside (154774-22-8) → benzyl 2,3-O-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside (154774-23-9)

Guidance literature:

With methanol; iodine; In dichloromethane; for 40h; Reflux; Inert atmosphere;

DOI:10.1039/c2ob25065a

Reference yield:

3,4,5-tribenzyloxybenzoic acid (1486-48-2) → benzyl 2,3-O-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside (154774-23-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 89 percent / 4-(dimethylamino)pyridine, 4-(dimethylamino)pyridine hydrochloride, 1,3-dicyclohexylcarbodiimide / CH₂Cl₂ / Heating

2: 100 percent / iodine / methanol; CH₂Cl₂ / 40 h / Heating

With dmap; iodine; 4-(dimethylamino)pyridine hydrochloride; dicyclohexyl-carbodiimide; In methanol; dichloromethane;

DOI:10.1021/ja00084a015

upstream raw materials:

3,4,5-tribenzyloxybenzoic acid

benzyl 4,6-O-benzylidene-β-D-glucopyranoside

benzyl 4,6-O-benzylidene-2,3-O-bis(3,4,5-tris(benzyloxy)benzoyl)-β-D-glucopyranoside