trans-NiI₂(2,6-Me₂C₆H₃NC)2

Base Information

• Chemical Name: trans-NiI₂(2,6-Me₂C₆H₃NC)2
• CAS No.: 135694-55-2
• Molecular Formula: C₁₈H₁₈I₂N₂Ni
• Molecular Weight: 574.853
• Mol file: 135694-55-2.mol

Synonyms:trans-NiI₂(2,6-Me₂C₆H₃NC)2

Chemical Property of trans-NiI₂(2,6-Me₂C₆H₃NC)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-NiI₂(2,6-Me₂C₆H₃NC)2

There total 2 articles about trans-NiI₂(2,6-Me₂C₆H₃NC)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

nickel(II) iodide (13462-90-3) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → trans-NiI2(2,6-Me2C6H3NC)2 (135694-55-2)

Guidance literature:

In dichloromethane; a mixt. of NiI2 and isocyanide-compd. in CH2Cl2 is stirred at room temp.; after 1 h the mixt. is filtered, solvent is removed in vac., the residue is crystd. from CH2Cl2-hexane; elem. anal.;

DOI:10.1246/bcsj.64.3376

Reference yield:

(3-4-η-3,4-diphenylcyclobut-3-ene-1,2-dione)tris(2,6-dimethylbenzene isocyanide)nickel (112262-30-3) → Ni(C6H3(CH3)2NC)2I2 (135694-55-2)

Guidance literature:

With iodine; In not given; byproducts: 3,4-diphenylcyclobut-3-ene-1,2-dione; room temp., N2 atm.;;

Reference yield: 85.0%

trans-NiI2(2,6-Me2C6H3NC)2 (135694-55-2) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → NiI2((CH3)2C6H3NC)3 (139010-71-2)

Guidance literature:

In dichloromethane; 2,6-xylyl isocyanide is added to a brown soln. of trans-NiI2(2,6-Me2C6H3NC)2 in CH2Cl2 at room temp., the soln. color turns blue; addn. of hexane gives blue crystals; elem. anal.;

DOI:10.1246/bcsj.64.3376

upstream raw materials:

nickel(II) iodide

2,6-dimethylphenyl isonitrile

(3-4-η-3,4-diphenylcyclobut-3-ene-1,2-dione)tris(2,6-dimethylbenzene isocyanide)nickel

Downstream raw materials:

tetrakis(2,6-dimethylphenyl isocyanide)nickel(O)

NiI₂((CH₃)2C₆H₃NC)3