1,2-dibromoferrocene

Base Information

• Chemical Name: 1,2-dibromoferrocene
• CAS No.: 238413-86-0
• Molecular Formula: C₁₀H₈Br₂Fe
• Molecular Weight: 343.829
• Mol file: 238413-86-0.mol

Synonyms:1,2-dibromoferrocene

Chemical Property of 1,2-dibromoferrocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-dibromoferrocene

There total 1 articles about 1,2-dibromoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

1,1,2,2-tetrabromoethane (79-27-6) + 1,1'-dibromoferrocene (1293-65-8) → ferrocene (102-54-5,55404-68-7) + 1,2-dibromoferrocene (238413-86-0)

Guidance literature:

With tetramethylpiperidine; n-butyl lithium; In tetrahydrofuran; hexane; Schlenk techniques used under N2 or Ar, THF soln. of (BrC5H4)2Fe (25.0 mmol) treated at -70°C with soln. of nBuLi (25.0 mmol), after 30 min TMP (25.0 mmol) added, stirred for 3 h at -30--40°C, C2H2Br4 (25.0 mmol) added at -70°C; allowed to warm to ambient temp. for >18 h, H2O added, aq. phase separated, extracted with Et2O, dried over MgSO4, evaporated, chromd. (neutral alumina, hexane), FcH removed by sublimation; NMR;

DOI:10.1016/j.jorganchem.2010.12.028

upstream raw materials:

1,1,2,2-tetrabromoethane

1,1'-dibromoferrocene