S-phenyl tetra-O-acetyl-1-deuterio-1-thio-α-D-mannopyranoside

Base Information

• Chemical Name: S-phenyl tetra-O-acetyl-1-deuterio-1-thio-α-D-mannopyranoside
• CAS No.: 810687-41-3
• Molecular Formula: C₂₀H₂₄O₉S
• Molecular Weight: 441.463
• Mol file: 810687-41-3.mol

Synonyms:S-phenyl tetra-O-acetyl-1-deuterio-1-thio-α-D-mannopyranoside

Chemical Property of S-phenyl tetra-O-acetyl-1-deuterio-1-thio-α-D-mannopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of S-phenyl tetra-O-acetyl-1-deuterio-1-thio-α-D-mannopyranoside

There total 1 articles about S-phenyl tetra-O-acetyl-1-deuterio-1-thio-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thiophenol (108-98-5) + C16H21(2)HO11 → S-phenyl tetra-O-acetyl-1-deuterio-1-thio-α-D-mannopyranoside (810687-41-3)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 14h;

DOI:10.1002/anie.200453688

Reference yield: 86.0%

S-phenyl tetra-O-acetyl-1-deuterio-1-thio-α-D-mannopyranoside (810687-41-3) → S-phenyl 1-deuterio-1-thio-α-D-mannopyranoside (810687-36-6)

Guidance literature:

With sodium methylate; In methanol; for 4h;

DOI:10.1002/anie.200453688

Reference yield:

S-phenyl tetra-O-acetyl-1-deuterio-1-thio-α-D-mannopyranoside (810687-41-3) → S-phenyl 4,6-O-α-deuteriobenzylidene-1-deuterio-1-thio-α-D-mannopyranoside

Guidance literature:

Multi-step reaction with 2 steps

1: 86 percent / sodium methoxide / methanol / 4 h

2: 55 percent / p-toluenesulfonic acid / dimethylformamide / 5 h / 60 °C

With sodium methylate; toluene-4-sulfonic acid; In methanol; N,N-dimethyl-formamide;

DOI:10.1002/anie.200453688

upstream raw materials:

thiophenol

Downstream raw materials:

S-phenyl 1-deuterio-1-thio-α-D-mannopyranoside