(2S,3aR,6S,7aR)-1-benzyl 2-methyl 3a,6-dihydroxy-3,3a,7,7a-tetrahydro-1H-indole-1,2(2H,6H)-dicarboxylate

Base Information

Chemical Name:(2S,3aR,6S,7aR)-1-benzyl 2-methyl 3a,6-dihydroxy-3,3a,7,7a-tetrahydro-1H-indole-1,2(2H,6H)-dicarboxylate
CAS No.:185394-34-7
Molecular Formula:C₁₈H₂₁NO₆
Molecular Weight:347.368
Hs Code.:

Synonyms:(2S,3aR,6S,7aR)-1-benzyl 2-methyl 3a,6-dihydroxy-3,3a,7,7a-tetrahydro-1H-indole-1,2(2H,6H)-dicarboxylate

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Chemical Property of (2S,3aR,6S,7aR)-1-benzyl 2-methyl 3a,6-dihydroxy-3,3a,7,7a-tetrahydro-1H-indole-1,2(2H,6H)-dicarboxylate

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Technology Process of (2S,3aR,6S,7aR)-1-benzyl 2-methyl 3a,6-dihydroxy-3,3a,7,7a-tetrahydro-1H-indole-1,2(2H,6H)-dicarboxylate

There total 1 articles about (2S,3aR,6S,7aR)-1-benzyl 2-methyl 3a,6-dihydroxy-3,3a,7,7a-tetrahydro-1H-indole-1,2(2H,6H)-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 144534-49-6
(2S,3aR,7aR)-3a-hydroxy-6-oxo-2,3,3a,6,7,7a-hexahydroindole-1,2-dicarboxylic acid 1-benzyl ester 2-methyl ester

: 185394-34-7
(2S,3aR,6S,7aR)-1-benzyl 2-methyl 3a,6-dihydroxy-3,3a,7,7a-tetrahydro-1H-indole-1,2(2H,6H)-dicarboxylate

Guidance literature:: With sodium tetrahydroborate; cerium(III) chloride; In methanol; for 0.166667h;
DOI:10.1016/0040-4020(96)00871-X

Reference yield: 90.0%

: 108-24-7
acetic anhydride

: 185394-34-7
(2S,3aR,6S,7aR)-1-benzyl 2-methyl 3a,6-dihydroxy-3,3a,7,7a-tetrahydro-1H-indole-1,2(2H,6H)-dicarboxylate

: 185394-35-8
(2S-(2β,3aβ,6α,7aβ))-2,3,3a,6,7,7a-hexahydro-6-acetyloxy-3a-hydroxy-1H-indole-1,2-dicarboxylic acid 1-benzyl 2-methyl ester

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1016/0040-4020(96)00871-X

Reference yield: 78.0%

: 185394-34-7
(2S,3aR,6S,7aR)-1-benzyl 2-methyl 3a,6-dihydroxy-3,3a,7,7a-tetrahydro-1H-indole-1,2(2H,6H)-dicarboxylate

: (2S,3aS,6S,7aR)-1-benzyl 2-methyl 3a,4,5,6-tetrahydroxyhexahydro-1H-indole-1,2(2H,3H)-dicarboxylate

Guidance literature:: With osmium(VIII) oxide; methanesulfonamide; 4-methylmorpholine N-oxide; In tetrahydrofuran; water; at 20 ℃; for 72h;
DOI:10.1021/jo801552j