1,1'-(1,23-dotriacontanediyl)bis<2-<(7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl>-3-benzyl-sn-glycerol>

Base Information

• Chemical Name: 1,1'-(1,23-dotriacontanediyl)bis<2-<(7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl>-3-benzyl-sn-glycerol>
• CAS No.: 136463-11-1
• Molecular Formula: C₉₂H₁₆₆O₆
• Molecular Weight: 1368.33
• Mol file: 136463-11-1.mol

Synonyms:1,1'-(1,23-dotriacontanediyl)bis<2-<(7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl>-3-benzyl-sn-glycerol>

Chemical Property of 1,1'-(1,23-dotriacontanediyl)bis<2-<(7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl>-3-benzyl-sn-glycerol>

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1'-(1,23-dotriacontanediyl)bis<2-<(7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl>-3-benzyl-sn-glycerol>

There total 3 articles about 1,1'-(1,23-dotriacontanediyl)bis<2-<(7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl>-3-benzyl-sn-glycerol> which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

isophytol (505-32-8) → 1,1'-(1,23-dotriacontanediyl)bis<2-<(7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl>-3-benzyl-sn-glycerol> (136463-11-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 99 percent / PBr₃, pyridine / hexane / 3 h / -10 - -7 °C

2: NaH / tetrahydrofuran / 20 h / Heating

With pyridine; phosphorus tribromide; sodium hydride; In tetrahydrofuran; hexane;

DOI:10.1246/bcsj.64.2088

Reference yield:

1,1'-(1,32-dotriacontanediyl)bis(3-benzyl-sn-glycerol) (136463-10-0) → 1,1'-(1,23-dotriacontanediyl)bis<2-<(7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl>-3-benzyl-sn-glycerol> (136463-11-1)

Guidance literature:

Multi-step reaction with 2 steps

1: NaH / tetrahydrofuran / 1 h / Ambient temperature

2: NaH / tetrahydrofuran / 20 h / Heating

With sodium hydride; In tetrahydrofuran;

DOI:10.1246/bcsj.64.2088

Reference yield:

(7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl bromide (943232-38-0) + C52H88O6(2-)*2Na(1+) → 1,1'-(1,23-dotriacontanediyl)bis<2-<(7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl>-3-benzyl-sn-glycerol> (136463-11-1)

Guidance literature:

With sodium hydride; In tetrahydrofuran; for 20h; Heating;

DOI:10.1246/bcsj.64.2088

upstream raw materials:

(7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl bromide

isophytol

1,1'-(1,32-dotriacontanediyl)bis(3-benzyl-sn-glycerol)

Downstream raw materials:

1,1'-(1,23-dotriacontanediyl)bis<2-<(3RS,7R,11R)-3,7,11,15-tetramethylhexadecyl>-3-benzyl-sn-glycerol>