[Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Ni(SCH₂CH₂PPh₂)][PF₆]

Base Information

• Chemical Name: [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Ni(SCH₂CH₂PPh₂)][PF₆]
• CAS No.: 847830-73-3
• Molecular Formula: C₂₅H₃₈N₂Ni₂PS₃*F₆P
• Molecular Weight: 756.106

Synonyms:[Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Ni(SCH₂CH₂PPh₂)][PF₆]

Chemical Property of [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Ni(SCH₂CH₂PPh₂)][PF₆]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Ni(SCH₂CH₂PPh₂)][PF₆]

There total 1 articles about [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Ni(SCH₂CH₂PPh₂)][PF₆] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

sodium hexaflorophosphate + [N,N'-diethyl-3,7-diazanonane-1,9-dithiolato]nickel(II) (176445-58-2) + [Ni2((μ2-S)CH2CH2PPh2)2Cl2] (85776-79-0,847830-84-6) → [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Ni(SCH2CH2PPh2)][PF6] (847830-73-3)

Guidance literature:

In tetrahydrofuran; under pure N2 atm.; to suspn. of Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate) in THF added dropwise soln. of (Ni(SCH2CH2PPh2)Cl)2 in THF; suspn. of NaPF6 in THF added; soln. stirred for 3 h; mixt. filtered through Celite; filtrate concd. to dryness; solid extd. from residue (CH2Cl2); extract filtered; ether was diffused into filtrate; elem. anal.;

DOI:10.1021/ja040222n

Reference yield:

[Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Ni(SCH2CH2PPh2)][PF6] (847830-73-3) + [Bu4N]2[Fe4S4(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene(3-))(triflate)] → [Bu4N][Fe4S4(1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris(p-tolylthio)benzene(3-))Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)]

Guidance literature:

In dichloromethane-d2; byproducts: CF3SO3(1-); monitored by NMR-spectroscopy;

DOI:10.1021/ja040222n

upstream raw materials:

[N,N'-diethyl-3,7-diazanonane-1,9-dithiolato]nickel(II)

[Ni2((μ2-S)CH2CH2PPh2)2Cl2]

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 847830-73-3 [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Ni(SCH₂CH₂PPh₂)][PF₆]

Send

Send

Metric Ton KG G Pound L ML

Send

Send