(2R,3R,4R)-3-(4-methoxybenzyloxy)-2-pentyl-3,4-dihydro-2H-pyran-4-yl 3-oxopentanoate

Base Information

Chemical Name:(2R,3R,4R)-3-(4-methoxybenzyloxy)-2-pentyl-3,4-dihydro-2H-pyran-4-yl 3-oxopentanoate
CAS No.:1590239-95-4
Molecular Formula:C₂₃H₃₂O₆
Molecular Weight:404.503
Hs Code.:

Synonyms:(2R,3R,4R)-3-(4-methoxybenzyloxy)-2-pentyl-3,4-dihydro-2H-pyran-4-yl 3-oxopentanoate

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Chemical Property of (2R,3R,4R)-3-(4-methoxybenzyloxy)-2-pentyl-3,4-dihydro-2H-pyran-4-yl 3-oxopentanoate

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Technology Process of (2R,3R,4R)-3-(4-methoxybenzyloxy)-2-pentyl-3,4-dihydro-2H-pyran-4-yl 3-oxopentanoate

There total 2 articles about (2R,3R,4R)-3-(4-methoxybenzyloxy)-2-pentyl-3,4-dihydro-2H-pyran-4-yl 3-oxopentanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 196704-96-8
4-O-p-methoxybenzyl-D-glucal

: 1590239-95-4
(2R,3R,4R)-3-(4-methoxybenzyloxy)-2-pentyl-3,4-dihydro-2H-pyran-4-yl 3-oxopentanoate

Guidance literature:: Multi-step reaction with 3 steps

1: triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere

2: copper(l) iodide / tetrahydrofuran / -30 - 20 °C

3: dmap; dicyclohexyl-carbodiimide / dichloromethane / 4 h / 0 °C

With dmap; copper(l) iodide; triethylamine; dicyclohexyl-carbodiimide; In tetrahydrofuran; dichloromethane;
DOI:10.1002/chem.201303328

Reference yield:

: 1590239-90-9
5-p-methoxybenzyl-tosyl-D-glycal

: 1590239-95-4
(2R,3R,4R)-3-(4-methoxybenzyloxy)-2-pentyl-3,4-dihydro-2H-pyran-4-yl 3-oxopentanoate

Guidance literature:: Multi-step reaction with 2 steps

1: copper(l) iodide / tetrahydrofuran / -30 - 20 °C

2: dmap; dicyclohexyl-carbodiimide / dichloromethane / 4 h / 0 °C

With dmap; copper(l) iodide; dicyclohexyl-carbodiimide; In tetrahydrofuran; dichloromethane;
DOI:10.1002/chem.201303328

Reference yield: 87.0%

: 1590239-95-4
(2R,3R,4R)-3-(4-methoxybenzyloxy)-2-pentyl-3,4-dihydro-2H-pyran-4-yl 3-oxopentanoate

: 1590239-97-6
1-((2S,5S,6R)-5-(4-methoxybenzyloxy)-6-pentyl-5,6-dihydro-2H-pyran-2-yl)butan-2-one

Guidance literature:: With 1,1'-bis(di-tertbutylphosphino)ferrocene; palladium diacetate; In toluene; at 60 ℃; for 6h; diastereoselective reaction; Schlenk technique; Inert atmosphere;
DOI:10.1002/chem.201303328